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Coordination chemistry problem
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[QUOTE="Amitkumarr, post: 6366832, member: 679806"] [B]Homework Statement:[/B] How many of the following are the correct characteristics for the following complex(see attached figure). (i) It is a chelating complex (ii) It has two optically active isomer (iii) It is the polymerisation isomer of(see attached figure). (iv) It has total three unpaired electrons (v) There are four octahedron in the complex (vi) All electrons of central metal atoms are present in non axial d-orbitals. [B]Relevant Equations:[/B] No relevant equations.Based on theory. My attempt- 1)The given ligand forms chelate rings,so it should be a chelating complex. 2)It has no plane of symmetry (P.O.S),so it is optically active(octahedral complex) and should have 2 optically active isomers. 3)They are not polymerisation isomers because they have different emperical formula. 5) According to me there should be 3 octahedron in the complex. For options 4 and 6,I am unable to get the oxidation state of Cr(central atom) and the overall charge of this ligand.What should be the contribution of the OH groups in the charge of this ligand? Also,are my justifications correct? [/QUOTE]
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Coordination chemistry problem
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