Determination of iron by redox titration

In summary, the problem involves a 2.893 g sample of an unknown containing iron and 28.45 mL of a permanganate solution to determine the % Fe in the unknown. The missing information is provided in Pre-Laboratory question 3 and the starting point is to write the balanced reaction. However, it is not encouraged to solve the problem until enough effort has been shown by the original poster.
  • #1
brittni8924
1
0
If a 2.893 g sample of an unknown containing iron requires 28.45 mL of the permanganate solution described in Pre-Laboratory question 3 to reach the endpoint what is the % Fe in the unknown?
 
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  • #2
Start with the reaction equation.
 
  • #3
brittni8924 said:
If a 2.893 g sample of an unknown containing iron requires 28.45 mL of the permanganate solution described in Pre-Laboratory question 3 to reach the endpoint what is the % Fe in the unknown?

The problem statement is missing some information.
 
  • #4
I suppose the missing information was listed in the question 3.

Still, reaction equation is a starting point.
 
  • #5
Borek said:
I suppose the missing information was listed in the question 3.

Still, reaction equation is a starting point.

brittni8924,
What if you were to first write the balanced reaction, and then solve (or let one of us solve) the problem purely symbolically; then, you would clearly see what information is missing (but we are not encouraged to solve problems in this board until the original poster puts in and shows enough effort).
 

1. What is the purpose of determining iron by redox titration?

The purpose of determining iron by redox titration is to accurately measure the amount of iron present in a sample. This can be useful in various industries, such as food and pharmaceuticals, to ensure the quality and safety of products.

2. What is the principle behind redox titration for iron determination?

The principle behind redox titration for iron determination is based on the reaction between iron ions and a titrant, typically a solution of potassium permanganate. Iron ions are oxidized by the permanganate ions, and the endpoint of the reaction is detected using an indicator.

3. How is the concentration of iron calculated from the titration results?

The concentration of iron can be calculated using the titration results by using the following formula: (volume of titrant x molarity of titrant x number of iron ions per molecule) / volume of sample. The number of iron ions per molecule is determined by the balanced chemical equation of the redox reaction.

4. What are the limitations of using redox titration for iron determination?

One limitation of using redox titration for iron determination is that it requires a relatively large sample size, which may not be practical in certain situations. Additionally, the accuracy of the results can be affected by the purity of the sample and the presence of other substances that can interfere with the redox reaction.

5. How can the accuracy of redox titration for iron determination be improved?

The accuracy of redox titration for iron determination can be improved by carefully controlling the experimental conditions, such as using a pure sample and properly calibrating the titrant solution. It is also important to perform multiple trials and calculate the average to reduce errors. Alternatively, other methods such as atomic absorption spectroscopy can be used for more precise and accurate results.

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