Determination of L absorption edge

In summary, the L absorption edge is a characteristic energy level at which the absorption of X-rays by an element increases significantly. It is determined using X-ray absorption spectroscopy and can provide information about the electronic structure of an element. The L absorption edge can be affected by various factors and is widely used in materials science, environmental science, and biological research.
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Homework Statement



In uranium (Z=92) the K absorption edge is 0.107 Å and the Kα line is 0.126 Å. Determine the wavelength of the L absorption edge.

Homework Equations



K-edge: EK= (Z-1)2*13.6
L-edge: EL= (Z-σL)2*13.6*1/4
what is σ and how was calculated.
Characteristic X-rays: Ex = h*ν= h*c/λ= ΔEkin = Ekin(i)-Ekin(f)
Bremsstrahlung: Emax=Ekin(i)

The Attempt at a Solution


λL= 0.71 Å
 
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Any answer or clearance for this question please?
 

1. What is the L absorption edge?

The L absorption edge is a characteristic energy level at which the absorption of X-rays by an element increases significantly. This energy level corresponds to the binding energy of electrons in the L shell of an atom.

2. How is the L absorption edge determined?

The L absorption edge is determined using X-ray absorption spectroscopy (XAS). This involves bombarding a sample with X-rays of varying energies and measuring the absorption of these X-rays. The energy at which there is a sharp increase in absorption is the L absorption edge.

3. What information can be obtained from the L absorption edge?

The L absorption edge can provide information about the electronic structure of an element, including the number of electrons in the L shell and their binding energies. It can also be used to identify the presence of specific elements in a sample.

4. What factors can affect the L absorption edge?

The L absorption edge can be affected by the chemical environment of the element, the oxidation state of the element, and the presence of neighboring atoms. It can also be affected by the energy and intensity of the incident X-rays.

5. How is the L absorption edge used in practical applications?

The L absorption edge is widely used in various fields, including materials science, environmental science, and biological research. It can be used to study the structure and composition of materials, identify contaminants in the environment, and analyze the chemical makeup of biological samples.

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