How Does Optical Absorption Threshold Measure the Band Gap in Semiconductors?

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In summary: So the threshold of continuous absorption would be the point at which the incoming energy is low enough to measure absorption, but not so low that it would count as a bound state?
  • #1
ehrenfest
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[SOLVED] direct absorption proces

Homework Statement



My solid-state physics book (Kittel) says the following in the chapter about semiconductors:

"In a direct absorption process the threshold of continuous optical absorption at frequency [itex]\omega_g[/itex] measure the band gap [itex]E_g = \hbar \omega_g[/itex]",

Apparently this is a definition, so it is hard to argue with it, but can someone explain what the "threshold of continuous optical absorption" means and how that could measure the band gap?

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  • #2
ehrenfest said:

Homework Statement



My solid-state physics book (Kittel) says the following in the chapter about semiconductors:

"In a direct absorption process the threshold of continuous optical absorption at frequency [itex]\omega_g[/itex] measure the band gap [itex]E_g = \hbar \omega_g[/itex]",

Apparently this is a definition, so it is hard to argue with it, but can someone explain what the "threshold of continuous optical absorption" means and how that could measure the band gap?

by "threshold" of absorption he means the lowest (incoming beam) energy at which you measure absorption. below this energy there will be no absorption and the incoming beam will simply pass through the material as if it were completely transpartent.

I.e., the absorption spectrum should look something like a theta function
[tex]
\theta(\hbar \omega - E_g)
[/tex]
times some other smooth function

in real life the absorption spectrum is not a perfect step function, but it does "turn on" fairly sharply at "threshold" (sharply enough so that we can tell what the threshold incoming energy is).

The reason he uses the word "continuous" is that there actually can be some absorption "below threshold" due to bound states, but that absorption shows up in the spectrum as discrete little peaks (like delta function, but not infinity sharp), not as a continuous spectrum.
 
  • #3
olgranpappy said:
by "threshold" of absorption he means the lowest (incoming beam) energy at which you measure absorption. below this energy there will be no absorption and the incoming beam will simply pass through the material as if it were completely transpartent.

I.e., the absorption spectrum should look something like a theta function
[tex]
\theta(\hbar \omega - E_g)
[/tex]
times some other smooth function

in real life the absorption spectrum is not a perfect step function, but it does "turn on" fairly sharply at "threshold" (sharply enough so that we can tell what the threshold incoming energy is).

The reason he uses the word "continuous" is that there actually can be some absorption "below threshold" due to bound states, but that absorption shows up in the spectrum as discrete little peaks (like delta function, but not infinity sharp), not as a continuous spectrum.

I see, thanks.
 

1. What is a direct absorption process?

A direct absorption process is a method used in spectroscopy to measure the absorption of light by a substance. It involves shining a beam of light, typically in the ultraviolet or visible range, through a sample and measuring the amount of light that is absorbed by the sample. This can provide information about the chemical composition and structure of the sample.

2. How does a direct absorption process work?

In a direct absorption process, a light source emits a beam of light that passes through a sample. The sample absorbs some of the light, while the rest is transmitted through the sample. A detector measures the intensity of the transmitted light and compares it to the intensity of the original light beam. The difference in intensity is used to calculate the amount of light absorbed by the sample.

3. What types of samples can be analyzed using a direct absorption process?

Direct absorption processes can be used to analyze a wide range of samples, including liquids, gases, and solids. It can be applied to pure substances, mixtures, and solutions. The technique is commonly used in chemistry, biochemistry, and environmental science to study the composition and properties of various substances.

4. What are the advantages of using a direct absorption process?

One of the main advantages of a direct absorption process is its high sensitivity and accuracy in measuring the absorption of light by a sample. It also allows for a rapid analysis of samples with minimal sample preparation. Additionally, it can provide information about the concentration, identity, and structure of chemical compounds in a sample.

5. Are there any limitations to using a direct absorption process?

One limitation of using a direct absorption process is that it can only measure the absorption of light in the ultraviolet or visible range. This means that it cannot be used to analyze samples that do not absorb in these regions, such as pure gases. Additionally, the technique may be affected by factors such as light scattering and sample turbidity, which can affect the accuracy of the results.

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