- #36
sophiecentaur
Science Advisor
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Personally, I always see categorising as seriously getting in the way of understanding. Your first category (electrons producing photons) is not a realistic one (for the reasons you have been given by me and others). The vibrational category is limited to isolated molecules (at least, the way you are thinking of it). Can you suggest a rotational transition that can exist at all in a solid?desta41 said:questions about the categories of transitions
This is your own personal sub-set of Physics and I suggest you read a (modern) textbook that deals with the solid state and that may give you a clue as to why your model doesn't explain enough of what we see around us.
You want to use your model to explain black body radiation. A monatomic gas at high temperature cannot produce a black body spectrum. The colours you would see if you took an envelope of Hydrogen gas and somehow put it in thermal equilibrium (i.e. heat it up) in a furnace at 1000°C. Would you expect it to be 'red hot'?
Yo get black body spectrum, you need a condensed arrangement of atoms so that transitions are 'available' amongst all the energy bands. This stuff is way beyond the elementary behaviour of idealised gaseous atoms and molecules.