Electron Effective Mass and Effective Mass Theory in Semiconductors

In summary, the concept of "effective mass" was introduced in semiconductors for two main reasons: to describe properties that depend on it, such as mobility, and to simplify the many-body problem of interactions between electrons by creating a "quasiparticle" with a renormalized mass. In simple metals, the effective mass is related to the orbital overlap, with more overlapping orbitals resulting in free electron-like states and less overlap resulting in a higher effective mass. However, this concept cannot be applied to deep defects in semiconductors due to its mean peculiarities and approximations.
  • #1
mendes
40
0
I would like to ask about the reason why the electron "effective mass" was introduced in semiconductors. What is its' usefulness ?

And also about the so-called "effective mass theory" used to calculate energies for the shallow defects in semiconducors. What are mean pecularities and approximations of this theory and why we can't use it to calculate deep defects.

Thanks.
 
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  • #2
mendes said:
I would like to ask about the reason why the electron "effective mass" was introduced in semiconductors. What is its' usefulness ?

Er.. there are many properties that depends on the effective mass. The mobility is one example. So that's one reason why such a concept was introduced.

Another reason is that, within the Fermi Liquid Theory, we can lump all the many-body interactions into this "renormalized" mass (effective mass), creating a "quasiparticle", rather than a bare electron. This allows us to go from a many-body problem (difficult), to many one-body problem (easier).

Zz.
 
  • #3
Simply because you can behave electrons in semiconductors like in electrons in vacuum with effective mass.
 
  • #4
in simple metals, the effective mass can be related to the orbital overlap. strongly overlapping orbitals give states with free electron like character, whereas a reduced overlap increases the effective mass..
 

1. What is the effective mass of an electron in semiconductors?

The effective mass of an electron in semiconductors refers to the mass that an electron appears to have when moving in a semiconductor material under the influence of an applied electric field. It is different from the actual mass of an electron and is dependent on the material's crystal lattice structure and the direction of movement.

2. How is the effective mass of an electron determined?

The effective mass of an electron is determined through experimental measurements and theoretical calculations. One common method is to measure the electron's velocity and the applied electric field to calculate the effective mass using the equation m* = h^2/(dE/dk), where m* is the effective mass, h is Planck's constant, E is the energy, and k is the wave vector.

3. What is the significance of the effective mass in semiconductors?

The effective mass is a crucial parameter in the study of semiconductors as it affects the electron's behavior and properties in the material. It plays a significant role in determining the electrical and optical properties of semiconductors, such as conductivity, mobility, and bandgap.

4. How does the effective mass influence the band structure of semiconductors?

The effective mass has a direct impact on the shape and position of the energy bands in semiconductors. In materials with a lower effective mass, the energy bands are wider and closer together, while in materials with a higher effective mass, the energy bands are narrower and further apart. This affects the material's electrical conductivity and optical properties.

5. Can the effective mass be altered in semiconductors?

Yes, the effective mass of electrons in semiconductors can be altered by introducing impurities or defects into the material's crystal structure. This is known as doping and is a common method used to modify the electrical and optical properties of semiconductors for various applications.

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