# Energy and frequency question

Energy and frequency E=hv

I have a simple question that is that is E=3/2x Kb x T, where kb is boltzmann constant.
I understand that this is involve 3 degree of freedom, but as i was reading through the forum, i come across 1 equation stating E=kb x T. So is it true? and what application would this apply to?

And with regards to quantum physics, since kinetic energy= 1/2MV2, and =3/2kbT,
yet, λ=h/p=h/mv, where h is planck constand and p is momentum, and λ is wavelength.

Since λ=V/F, where v is velocity and F is frequency,
then this would mean that V/F=h/mv, and I would get hxF=mV2,
and since E=hxv, where E is energy, h is planck constant, and v is velocity,
would that mean that E=mV2 which I don't understand as I thought E was suppose to be 1/2mv2, yet now the 1/2 has disappear.

Thanks a lot for the help, a bit confused with all the energy, frequency and wavelength.

Last edited:

DrClaude
Mentor
I have a simple question that is that is E=3/2x Kb x T, where kb is boltzmann constant.
I understand that this is involve 3 degree of freedom, but as i was reading through the forum, i come across 1 equation stating E=kb x T. So is it true? and what application would this apply to?
The equipartition tells us that
$$\langle E \rangle = \frac{f}{2} k_\mathrm{B} T$$
i.e., each quadratic degree of freedom contributes ##k_\mathrm{B} T/2## to the average energy.

For kinetic energy only, since ##E \propto p_x^2 +p_y^2 + p_z^2##, there are ##f=3## quadratic degrees of freedom, from which we get the first equation in the OP.

The second equation is of course obtained for ##f=2##, which would be the case for, e.g., a 2D monatomic ideal gas or a harmonic oscillator (since ##E## is then obtained from the sum of a term in ##p^2## and a term in ##x^2##). The vibration of diatomic molecules is most often modeled as a harmonic oscillator.

And with regards to quantum physics, since kinetic energy= 1/2MV2, and =3/2kbT,
yet, λ=h/p=h/mv, where h is planck constand and p is momentum, and λ is wavelength.

Since λ=V/F, where v is velocity and F is frequency,
The latter ##\lambda## is the wavelength of a classical wave propagating at a velocity ##v##, and shouldn't be confused with the former ##\lambda##, which is the de Broglie wavelength.

• Greg Bernhardt