Deriving the Fermi Distribution: Fixed Particle Canonical Ensemble

In summary, the conversation discusses the use of different ensembles, specifically the canonical and grand-canonical ensemble, in deriving the Fermi distribution. While it is commonly believed that all ensembles are equal in the large N limit, there are exceptions. However, it is questioned why the canonical ensemble with a fixed number of particles is not used more often, as it is easier to calculate the grand-canonical partition function. The conversation also mentions a book that contains a derivation of the Fermi distribution using the canonical ensemble.
  • #1
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All derivations of the Fermidistribution uses a canonical ensemble with a chemical potential, which is the same as to say that the ensemble can exchange particles with a resevoir. But are the derivations still valid for the canonical ensemble with a fixed number of particles and why isn't this just used?
 
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  • #2
The calculation of the grand-canonical partition function is much easier than calculation of the canonical one.
There is a folk theorem that all ensembles are equal in the large N limit, although there are counter-examples.
However, I strongly doubt that "All" derivations of the Fermi distribution use a grand-canonical ensemble.
E.g. I think Thirrings book "Quantum Mathematical Physics: Atoms, Molecules and Large Systems" contains a derivation using the canonical ensemble.
 

1. What is the Fermi distribution?

The Fermi distribution, also known as the Fermi-Dirac distribution, is a probability distribution that describes the distribution of particles in a system at thermal equilibrium. It is used to calculate the probability of a particle occupying a particular energy state in a system of fermions, which are particles with half-integer spin such as electrons.

2. What is the fixed particle canonical ensemble?

The fixed particle canonical ensemble is a thermodynamic ensemble used to describe a system of particles with a fixed number of particles. This ensemble is particularly useful for studying systems with a fixed number of fermions, such as electrons in a metal.

3. How is the Fermi distribution derived in the fixed particle canonical ensemble?

The Fermi distribution is derived by maximizing the entropy of the system subject to constraints such as the number of particles and total energy. This results in a distribution that follows the Fermi-Dirac statistics, which takes into account the exclusion principle for fermions.

4. What are the assumptions made in deriving the Fermi distribution?

The derivation of the Fermi distribution assumes that the system is in thermal equilibrium, that the particles are non-interacting, and that the system is in a fixed volume. It also assumes that the energy levels are discrete and that the particles follow the Fermi-Dirac statistics.

5. What are the applications of the Fermi distribution in physics?

The Fermi distribution is used in various fields of physics, such as solid state physics, nuclear physics, and astrophysics. It is used to calculate the electronic properties of metals, the energy levels in nuclei, and the behavior of matter in extreme conditions, such as in white dwarfs and neutron stars.

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