• Support PF! Buy your school textbooks, materials and every day products Here!

Find Lattice Constant of NaCl

  • Thread starter paperstars
  • Start date
  • #1

Homework Statement



NaCl is a simple cubic lattice, with the Na and Cl atoms alternating positions. Assuming that the atoms are hard spheres with nearest neighbors touching, what is the lattice constant of NaCl? (The effective radius of Na is 1.0 angstroms, and the effective radius of Cl is 1.8 angstroms.)


Homework Equations



lattice constant = 2 * radius

=> a = 2r


The Attempt at a Solution



I did a = 2 (r1 + r2) = 2(1.0 + 1.8) = 5.6 angstroms. I've googled the lattice constant of NaCl to be 5.65 angstroms.

However, my solutions manual says that a = r1 + r2 = 1.0 + 1.8 = 2.8 angstroms is the correct answer.

I thought that the lattice constant is equal to the complete distance of the two atoms, from one end to the other, so that means 2r.

I'm wondering which answer is correct and why?
 

Answers and Replies

  • #2
Please help, I actually lost a little sleep last night trying to figure this out. :tongue:

I asked my professor and he didn't give me a straight answer on whether my method of thinking is correct or not. However, my impression from his response was my method was correct but on second thought, I'm having doubts.
 

Related Threads on Find Lattice Constant of NaCl

  • Last Post
Replies
4
Views
641
Replies
1
Views
872
Replies
1
Views
530
  • Last Post
Replies
12
Views
894
  • Last Post
Replies
2
Views
2K
  • Last Post
Replies
4
Views
20K
  • Last Post
Replies
19
Views
4K
Replies
0
Views
2K
  • Last Post
Replies
1
Views
5K
  • Last Post
Replies
1
Views
1K
Top