Solve First Law of Thermo Homework: (DT/DV)s = -(DP/DS)v

In summary, the first law of thermodynamics can be expressed as dU = TdS - PdV, where U represents internal energy and can be written in terms of any two of T, P, V, and S. The task is to prove that (DT/DV)s = -(DP/DS)v using the Maxwell relations. These relations state that if we have a function f(x,y), then the partial derivative of the partial derivative with respect to y is equal to the partial derivative of the partial derivative with respect to x. This means that (DA/Dy)x = (DB/Dx)y.
  • #1
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Homework Statement



First law can be written dU = TdS - PdV where the internal energy U may be written in terms of any two of T,P,V,S.

I have to show that (DT/DV)s = -(DP/DS)v

where D is partial d, and the subscripts s and v mean hold those constant..

Homework Equations





The Attempt at a Solution



Not really sure how to proceed at all?
 
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  • #2
This is one of the Maxwell relations.
If you have a function
[tex]f(x,y)=\left( \frac{\partial f}{\partial x} \right)_y dx + \left( \frac{\partial f}{\partial y} \right)_x dy = A dx + B dy[/tex]
then, according to
[tex]\frac{\partial}{y} \left( \frac{\partial f}{\partial x} \right) = \frac{\partial}{\partial x} \left( \frac{\partial f}{\partial y} \right)[/tex]
you have
[tex]\left( \frac{\partial A}{\partial y} \right)_x = \left( \frac{\partial B}{\partial x} \right)_y[/tex]
 

What is the first law of thermodynamics?

The first law of thermodynamics, also known as the law of conservation of energy, states that energy cannot be created or destroyed, but can only be transferred or converted from one form to another.

What does the equation (DT/DV)s = -(DP/DS)v mean?

This equation is known as the Maxwell relation and it relates the change in temperature (DT) to the change in volume (DV) at constant entropy (s) and the change in pressure (DP) to the change in entropy (DS) at constant volume (v).

Why is the first law of thermodynamics important?

The first law of thermodynamics is important because it helps us understand the principles of energy conservation and the relationships between different forms of energy. It also provides the basis for many important thermodynamic processes and calculations.

How do I solve problems using the first law of thermodynamics?

To solve problems using the first law of thermodynamics, you will need to understand the basic principles of energy conservation and the relationships between different forms of energy. You will also need to have a good understanding of the specific problem and the variables involved, and be able to apply the appropriate equations and calculations.

Can you give an example of a problem that can be solved using the first law of thermodynamics?

One example of a problem that can be solved using the first law of thermodynamics is calculating the change in internal energy of a gas as it expands at constant pressure. By applying the first law of thermodynamics, we can determine the change in internal energy based on the change in volume, pressure, and temperature of the gas.

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