Calculating Photon Energy Needed to Exceed Fused Silica Glass Band Gap

In summary, glass is transparent to visible light, but at high intensities, it can absorb light through a process called multiphoton absorption. This can occur when several photons with enough energy are absorbed at the same time, such as in two-photon absorption. To determine the minimum number of photons of 800nm light needed to exceed the band gap of fused silica glass, the equation Energy of photon = hc/\lambda can be used. After multiplying this energy by the energy in the band gap, the minimum number of photons can be calculated.
  • #1
vachan
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Glass is transparent to visibile light under normal conditions; however, at extremely high intensities, glass will absorb most of the light incident upon it. This works through a process known as multiphoton absorption. In this process, several photons are absorbed at the same time. If very intense light whose photons carry 2eV of energy is shined onto a material with a band gap of 4eV, that light can be absorbed through two-photon absorption, because two photons have the right amount of energy to bridge the band gap. What is the minimum number of photons of 800nm- light that are needed to equal or exceed the band gap of fused silica glass?

I tried Energy of photon= hc/[tex]\lambda[/tex]... but then after that i don't know what to do. ... i know that energy is the J/ photon... so i multiply it by the energy in the band.,... but didnt get it! anyone knows how to do it?!
 
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  • #2
never mind i got it..
 
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To calculate the minimum number of photons of 800nm light needed to exceed the band gap of fused silica glass, we can use the formula for energy of a photon: E = hc/λ, where h is Planck's constant (6.626 x 10^-34 J*s), c is the speed of light (3.00 x 10^8 m/s), and λ is the wavelength of light (800nm = 8.00 x 10^-7 m).

First, we need to determine the energy of a single photon of 800nm light:
E = (6.626 x 10^-34 J*s)(3.00 x 10^8 m/s)/(8.00 x 10^-7 m)
E = 2.48 x 10^-19 J

Next, we need to determine the band gap energy of fused silica glass, which is given as 4eV. We need to convert this to joules:
1eV = 1.602 x 10^-19 J
4eV = (4)(1.602 x 10^-19 J) = 6.41 x 10^-19 J

Now, we can calculate the minimum number of photons needed to exceed the band gap energy:
Number of photons = Band gap energy / Energy of a single photon
Number of photons = (6.41 x 10^-19 J) / (2.48 x 10^-19 J)
Number of photons = 2.58

This means that at least 2.58 photons of 800nm light are needed to exceed the band gap energy of fused silica glass. Since photons cannot be divided, we would need at least 3 photons to exceed the band gap energy.
 

What is fused silica glass?

Fused silica glass is a type of glass that is created by melting pure silica (SiO2) at extremely high temperatures and then cooling it rapidly. This results in a glass that is highly transparent and has a high resistance to thermal shock and chemical corrosion.

What is the band gap of fused silica glass?

The band gap of fused silica glass is approximately 9 electron volts (eV). This means that any photon with energy lower than 9 eV will not have enough energy to excite the electrons in the glass and cause them to move, resulting in a transparent material.

How is the photon energy needed to exceed the fused silica glass band gap calculated?

The photon energy needed to exceed the fused silica glass band gap can be calculated using the formula E = hc/λ, where E is the energy of the photon in joules, h is Planck's constant (6.626 x 10^-34 joule seconds), c is the speed of light (3.00 x 10^8 meters per second), and λ is the wavelength of the photon in meters. Simply plug in the band gap value of 9 eV and solve for λ to find the minimum wavelength needed to exceed the band gap.

What factors can affect the photon energy needed to exceed the fused silica glass band gap?

The photon energy needed to exceed the fused silica glass band gap can be affected by several factors, including the temperature of the glass, impurities or defects in the glass structure, and the intensity of the incident light. These factors can alter the band gap and therefore impact the energy required for photon absorption.

Why is it important to calculate the photon energy needed to exceed the fused silica glass band gap?

Calculating the photon energy needed to exceed the fused silica glass band gap is important for understanding the properties and behavior of this type of glass. It can also be useful in designing and optimizing optical devices that use fused silica glass, such as lenses, prisms, and windows. Additionally, this calculation can help in the development of new materials with specific optical properties by determining the appropriate energy level needed for photon absorption.

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