Is this Gas Expansion Problem a Quasi-Static Adiabatic Process?

In summary, the conversation discusses a problem involving a cylinder with an ideal gas at the bottom and a liquid at the top separated by a piston. The process involves adding heat to the gas and causing it to expand, resulting in the liquid spilling out. The question is whether this process is quasi-static adiabatic. It is determined that the expansion is not adiabatic, and the final temperature can be calculated using the equation of state for an ideal gas. The conversation also discusses finding the pressure and work done by the gas in this process.
  • #1
Terry Bing
48
6
MODERATOR'S NOTE: Moved from other forum, so no template

@Chestermiller
I am still having trouble figuring out if a given process is Quasi-static or not.
Consider the following case. The cylinder consists of an ideal gas at the bottom and a liquid of density ρ at the top separated by a piston of mass m and area A. Atmospheric pressure is p0. Again, piston and cylinder are insulating. Initially, the piston is at equilibrium. A heater is turned on in the gas. The gas will expand causing the liquid to spill out. Is this process a quasi-static adiabatic process? In this case there are no sudden changes.
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If so then the final temperature T2(when piston reaches the top) should satisfy
T2V2γ-1=T1V1γ-1.
For a monatomic gas, we have γ=5/2, which gives us T2=(0.5)3/2T1, [Since V2=2V1]
Is this correct?
 

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  • #2
Terry Bing said:
MODERATOR'S NOTE: Moved from other forum, so no template

@Chestermiller
I am still having trouble figuring out if a given process is Quasi-static or not.
Consider the following case. The cylinder consists of an ideal gas at the bottom and a liquid of density ρ at the top separated by a piston of mass m and area A. Atmospheric pressure is p0. Again, piston and cylinder are insulating. Initially, the piston is at equilibrium. A heater is turned on in the gas. The gas will expand causing the liquid to spill out. Is this process a quasi-static adiabatic process?
It is not adiabatic because heat is being added to the gas. If the heat is added gradually enough, the process is quasi static.
In this case there are no sudden changes.
View attachment 220845
If so then the final temperature T2(when piston reaches the top) should satisfy
T2V2γ-1=T1V1γ-1.
No. As I said, the expansion is not adiabatic, and this equation applies to an adiabatic reversible process.
For a monatomic gas, we have γ=5/2,
No. For a monatomic gas, ##\gamma = 5/3##
Is this correct?
No.

In this problem, you need to start out by determining the pressure as a function of the change in piston elevation x (so that the work can be determined and the final temperature can be determined). What is the pressure on the gas initially? What is the pressure on the gas after the piston has risen by a distance x? What is the pressure on the gas when the piston has risen a distance h?
 
  • #3
Chestermiller said:
In this problem, you need to start out by determining the pressure as a function of the change in piston elevation x (so that the work can be determined and the final temperature can be determined). What is the pressure on the gas initially? What is the pressure on the gas after the piston has risen by a distance x? What is the pressure on the gas when the piston has risen a distance h?
Thanks, I understand. I got half the answer. A number of hasty mistakes on my part in the attempt above. The process isn't adiabatic. It isn't given whether the gas is mono or diatomic, so we don't know γ.
At any instant of time, external pressure on the gas is Pext=P0+ρgy+mg/A, where y is the depth of the water layer. Work done by the gas
[tex] W=\int_{0}^{h} P_{ext} A dy= \int_{0}^{h} (P_0 A+\rho g y A+mg) dy=P_0 A h+\frac{1}{2} \rho g h^2 A+m g h [/tex]
Now If we know the heat supplied,
[tex] Q-W=\Delta U [/tex]
But Q is not given in the question. Also, we don't know γ to get ΔU in terms of T.
 
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  • #4
I got it. We can use equation of state for an ideal gas. Assuming the process is quasi-static, both initial and final states will be equilibrium states. Then
[tex] P_1 V_1 / T_1=P_2 V_2/ T_2 \\
\implies T_2=( \frac{V_2}{V_1}) (\frac{P_2}{P_1}) T_1 \\
\implies T_2=2(\frac{p_0 A+m g}{p_0 A+\rho g h A+m g}) T_1[/tex]
 
  • #5
Terry Bing said:
I got it. We can use equation of state for an ideal gas. Assuming the process is quasi-static, both initial and final states will be equilibrium states. Then
[tex] P_1 V_1 / T_1=P_2 V_2/ T_2 \\
\implies T_2=( \frac{V_2}{V_1}) (\frac{P_2}{P_1}) T_1 \\
\implies T_2=2(\frac{p_0 A+m g}{p_0 A+\rho g h A+m g}) T_1[/tex]
Very Good. It's just ##\Delta U=\frac{C_v}{R}\Delta (PV)##
 

What is the "Gas Expansion Problem"?

The "Gas Expansion Problem" refers to the phenomenon of a gas expanding when it is heated or when the pressure on it decreases. This can result in changes in temperature, volume, and pressure of the gas.

What causes gas expansion?

Gas expansion is caused by the increase in kinetic energy of the gas molecules when heated or when the pressure on it decreases. This increase in kinetic energy causes the molecules to move faster and spread out, resulting in an expansion of the gas.

What is the relationship between temperature and gas expansion?

According to Charles's Law, the volume of a gas is directly proportional to its temperature at constant pressure. This means that as the temperature of a gas increases, its volume will also increase, resulting in gas expansion.

How does gas expansion affect pressure?

As gas expands, its volume increases while its temperature remains constant. This results in a decrease in pressure, as there are now more molecules spread out in a larger volume, resulting in fewer collisions between molecules and the walls of the container.

What are some real-world examples of gas expansion?

Examples of gas expansion can be seen in everyday life, such as when a balloon is heated and expands, or when a tire is overinflated on a hot day and bursts due to gas expansion. Gas expansion is also the basis for many industrial processes, such as the expansion of natural gas in pipelines.

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