1. The problem statement, all variables and given/known data A voltaic cell at 25oC consists of Mn/Mn2+ and Cd/Cd2+ half-cells with an initial cell potential of +0.768 V. The [Mn2+] concentration is 0.500 M. Use the Nernst equation to calculate the [Cd2+] concentration in the Cd/Cd2+ half-cell. Cd+2(aq) + 2e- = Cd(s) . . . . . Eo = -0.40 V Mn+2(aq) + 2e- = Mn(s) . . . . . Eo = -1.18 V 2. Relevant equations Ecell = E(standard) cell - (RT/nF)ln Q 3. The attempt at a solution I was just wondering how do we know which reaction above, we need to flip and how do we determine which metal is oxidized and reduced in cells like this? Is it that the half-cell woth the more negative potential is more redilly reduced, thus thats the one you flip, to create the cell? I know how to use the nerst equation and find concentration, but am having trouble with Enot Cell because i dont know which eqn to flip.