Why is HCP more common than FCC in elemental compositions?

In summary, HCP (hexagonal close-packed) and FCC (face-centered cubic) are two common crystal structures found in elements, with the main difference being the arrangement of atoms within the lattice. Some elements that have an HCP structure include magnesium, titanium, zinc, and cobalt, while other elements can have either structure depending on various factors such as atom size and charge, temperature, and pressure. Both structures have unique properties, with HCP structures being more compact and dense, and FCC structures being more symmetrical and ductile. It is possible for an element to have both HCP and FCC structures under different conditions or through processes such as alloying.
  • #1
gibbo
1
0
This may be obvious but since the packing fraction for both hexagonal close packed and face centered cubic is the same (74% i believe) why is HCP more common in elemental compositions?
 
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  • #2
Well, I don't really know, but I noticed that a lot of the Lanthanoids and Actinoids are HCP, and if you exclude those two sections, the number of HCP and FCC elements are almost the same.

This is the sort of question that I doubt there is an intuitive answer to...it's all quantum mechanics!
 

1. What is the difference between HCP and FCC crystal structures in elements?

HCP (hexagonal close-packed) and FCC (face-centered cubic) are two of the most common crystal structures found in elements. The main difference between them lies in the arrangement of atoms within the crystal lattice. In HCP, the atoms are arranged in a hexagonal pattern, while in FCC, they are arranged in a cubic pattern with atoms at the corners and in the center of each face.

2. Which elements have an HCP crystal structure?

Some common elements that have an HCP crystal structure include magnesium, titanium, zinc, and cobalt. However, there are many other elements that can also form an HCP structure depending on the conditions they are in.

3. Why do some elements have an HCP structure while others have an FCC structure?

The crystal structure of an element is determined by a combination of factors, including the size and charge of its atoms, as well as the temperature and pressure at which it is formed. For example, smaller atoms with a higher charge tend to favor an HCP structure, while larger atoms with a lower charge tend to favor an FCC structure.

4. What are the properties of HCP and FCC structures in elements?

Both HCP and FCC structures have their own unique properties. For example, HCP structures tend to be more compact and have a higher density than FCC structures. On the other hand, FCC structures are more symmetrical and have a higher ductility, making them easier to deform under stress.

5. Can an element have both HCP and FCC structures?

It is possible for an element to have both HCP and FCC structures, depending on the conditions it is under. For example, at high temperatures, some elements can undergo a phase transition from HCP to FCC, resulting in a mixture of both structures within the same material. This can also happen due to the addition of impurities or through the process of alloying.

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