Inequivalent K and K' points in graphene

In summary, the K and K' points in monolayer graphene are inequivalent because they correspond to different vertices in the momentum space of the hexagonal Brillouin zone. While they have the same energy and threefold rotational symmetry, they are mirror images of each other and have opposite phases in their wavefunctions. This difference is important in band theory calculations and must be taken into account in order to fully understand the electronic structure of graphene.
  • #1
forever_physicist
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Good evening to everybody!
I have a question concerning monolayer graphene.
In all the papers I read it is well specified that K and K' in graphene are not equivalent points, but I didn't find anywhere where is the difference between them. Can anybody tell me where this difference is coming from theoretically and how can be detected?
 
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  • #2
The K and K’ points are inequivalent for the same reason the A and B sublattices of graphene are inequivalent. Here’s a picture:
https://images.app.goo.gl/1PnPU5HPaW4FZawD8
In the momentum space picture, remember that only the first (hexagonal) Brillouin zone is shown; the Brillouin zones actually tile the plane. So with that in mind, it’s clear that (e.g.) the K point occurs at a vertex with two hexagons below it and one hexagon above it, and the K’ point occurs at the mirror image vertex, with one hexagon below and two above. In other words, both K and K’ have threefold rotational symmetry, but they’re inversions of each other.
 
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  • #3
Ok but if this is the case, why when in a DFT calculation we use the Irreducible Brillouin Zone, we only consider K? In principle it is not enough to consider only 1/12 of the hexagon as everybody do, right?
 
  • #4
The electronic structure (edit: the band energy structure, not the wavefunctions) is going to be the same, but the wavefunction at the K point is related to the wavefunction at the K' point by time reversal symmetry. It's kind of a momentum space analogy to different enantiomers of a molecule: they have the same energy, but they are mirror images of each other. Another way you can think about it is that near the K (K') points, the Hamiltonian ends up having the same form as that of a massless spin 1/2 particle. But the phases of the wavefunction components differ by a sign change. So at the K point, you get a "left-handed"spinor and at the K' point you get a "right-handed" spinor. Here's a pretty good review:
https://cdn.journals.aps.org/files/sample-rmp-revtex4.pdf
 
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  • #5
In band theory,we label all eigenstates with nk. The k point is defined in the first Brillouin Zone of specific structure, due to equivalence of the two k points whose difference is an integer multiple of reciprocal lattice vectors. In the case you mentioned, K minus K‘ is not an integer multiple of reciprocal lattice vectors, so they are not equivalent points. Although they have same eigenvalues because of symmetry, they are absolutely inequivalent points
 
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1. What are inequivalent K and K' points in graphene?

Inequivalent K and K' points in graphene refer to two distinct points in the Brillouin zone of graphene's hexagonal lattice structure. These points have different coordinates and are related by a rotation of 60 degrees.

2. How are the K and K' points related to the electronic properties of graphene?

The K and K' points are important in determining the electronic properties of graphene. They are known as the Dirac points, where the conduction and valence bands touch, giving graphene its unique electronic properties.

3. Why are the K and K' points considered to be equivalent in graphene?

Although the K and K' points have different coordinates, they are considered to be equivalent in graphene due to the symmetry of the hexagonal lattice. This symmetry allows for the rotation of 60 degrees to transform one point into the other.

4. How do the K and K' points affect the band structure of graphene?

The K and K' points play a crucial role in the band structure of graphene. They are responsible for the linear dispersion of the energy bands, which is a unique feature of graphene's electronic structure.

5. Can the K and K' points be manipulated in graphene?

Yes, the K and K' points can be manipulated in graphene through various methods such as applying an electric field or introducing defects in the lattice. This manipulation can alter the electronic properties of graphene and open up new possibilities for its applications.

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