Understanding Line Spectra: Evidence of Atomic Energy Levels

In summary, a line spectrum is a type of spectrum that shows distinct lines representing different photon frequencies emitted when electrons in an atom fall from higher to lower energy levels. This provides evidence of energy levels in atoms and can be understood through the concept of photons and electron excitation. The basics of line spectra can be found in the hydrogen spectrum, and a good starting point for understanding this concept is through the Bohr model.
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Hello, can someone explain how a line spectrum works. How do they provide evidence of energy levels in atoms?

I would have thought that energy levels are to do with a different concept of Bands (Valence, Conduction) so how does a line spectrum provide evidence? :confused:
 
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  • #3
Thank you for the link.


This is what I am understanding:

Photons are associated with a particular energy and allow Electrons to change levels. Electrons are excited to higher levels (by emitting Photons) and when they fall back to lower levels, light is emitted. Different frequencies create different light and this makes up a line spectrum.

Is it correct?
 
  • #4
I'd phrase it this way: When an electron falls from a higher energy level to a lower energy level, a photon is emitted whose frequency is proportional to the change in energy. The various energy levels and their differences determine the various photon frequencies, which form the "lines" of the spectrum (as opposed to a continuous spectrum).
 
  • #5
A good place to start: http://www.colorado.edu/physics/2000/quantumzone/bohr.html
 
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1. What is a line spectrum?

A line spectrum is a pattern of lines seen in the light emitted by an atom. Each line in the spectrum corresponds to a specific energy level of the atom's electrons.

2. How is a line spectrum produced?

A line spectrum is produced when an atom absorbs energy, causing its electrons to jump to higher energy levels. When the electrons return to their original energy levels, they emit energy in the form of light, creating a unique line spectrum for each element.

3. What evidence do line spectra provide for atomic energy levels?

Line spectra provide direct evidence for the existence of discrete energy levels in atoms. Each line in the spectrum corresponds to a specific energy level, and the gaps between the lines represent the energy differences between these levels. This supports the idea that electrons can only exist at certain energy levels in an atom, rather than being able to occupy any energy level.

4. How can line spectra be used to identify elements?

Each element has a unique line spectrum, so by analyzing the pattern of lines in a spectrum, scientists can determine which element is present. This technique, known as spectroscopy, is commonly used in astronomy and chemistry to identify the composition of stars and other celestial objects.

5. What other applications does the study of line spectra have?

Aside from identifying elements, line spectra also have applications in fields such as forensic science, where they can be used to identify unknown substances found at a crime scene. Additionally, the study of line spectra has led to a deeper understanding of atomic structure and the development of quantum mechanics.

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