Finding the Volume of a Unit Cell

In summary, the unit cell of a crystal lattice is a parallelepiped with vectors u, v, and w. The lengths of u, v, and w are 1, 2, and 3, respectively. The angles between the vectors are [u, v] = pi/4, [u, w] = pi/3, and [v, w] = pi/6. To determine the volume of the unit cell, we can use the formula V(w, u, v) = w scalar with (u x v). However, it is not possible to find the angle between w and u x v. One approach is to choose an orthonormal basis with u = (1,0,0
  • #1
surajalok
19
0

Homework Statement


Unit cell of a crystal lattice is a parallelepiped spanned by the vectors u, v, w vectors have lengths of 1, 2 resp3 (le). angles between the vectors is
[u, v] = pi / 4
[u, w] = pi / 3
[v, w] = pi / 6
Determine the volume of the unit cell.



Homework Equations


How do you solve this problem?

The Attempt at a Solution


volume = V (w, u, v) = w scalar with (u x v)
I can determine | uxv | = sqrt (2)
if I can find out the angle between
w and uxv then the problem is solved but it is not possible to get this angle.
 
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  • #2
may not be elegant, but how about noticing u is perpindicular to v, then if
|u| = 1
|v| = 2
|w| = 3

then choose an orthonormal basis such that
u = (1,0,0)
v = (0,2,0)

not let w = (a,b,c) with a^2 + b^2 + c^2 = 3^2, now you know
u.w = |u||w|cos(pi/3)
v.w = |v||w|cos(pi/6)
 
  • #3
lanedance said:
may not be elegant, but how about noticing u is perpindicular to v, then if
|u| = 1
|v| = 2
|w| = 3

then choose an orthonormal basis such that
u = (1,0,0)
v = (0,2,0)

not let w = (a,b,c) with a^2 + b^2 + c^2 = 3^2, now you know
u.w = |u||w|cos(pi/3)
v.w = |v||w|cos(pi/6)

[u, v] = pi / 4
[u, v] is not pi/2

i said something in the book about det(A^T A)
 
  • #4
fair bump, but you could do the same thing with
[tex] u = (1,0,0) [/tex]
[tex] v = (1,1,0) [/tex]
 
  • #5
in fact i think it follow pretty quickly form there...
 
  • #6
i don't know what i should do now?
we don't know anything about w.
I the book it said that examine det(A^T A)
colonnvektors in A are u,v,w.
 
  • #7
anyone?
 

What is the definition of volume?

Volume is the amount of space occupied by an object or substance.

What is a unit cell?

A unit cell is the smallest repeating unit of a crystal lattice, which can be used to represent the entire crystal structure.

Why is it important to find the volume of a unit cell?

Knowing the volume of a unit cell is important in determining the overall density and properties of a crystal, and can also help in identifying the type of crystal lattice present.

How do you calculate the volume of a unit cell?

The volume of a unit cell can be calculated by multiplying the lengths of its edges, as well as taking into account the angles between the edges, depending on the type of crystal lattice.

What are some techniques for finding the volume of a unit cell?

Some techniques for finding the volume of a unit cell include X-ray diffraction, electron diffraction, and computer modeling using software such as VESTA or CrystalMaker.

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