What causes the drop of latent heat at lower temperatures in liquid helium?

In summary, the article discusses the dependency of liquid helium's latent heat of evaporation on temperature, specifically the conspicuous maximum observed in the graph and table presented in Section 16. This maximum occurs at around 3.1 K and 94 J/mol for 4He. The article also mentions a similar graph for 3He, with a lower heat of evaporation and lower temperature for the maximum. The drop in latent heat at higher temperatures is a common occurrence in liquids due to thermal expansion and increased vapor density. However, the reason for the drop in latent heat at lower temperatures is still unknown and not commonly discussed. Comment 5 on page 48 states that at low temperatures, the latent heat can be calculated using the equation L
  • #1
snorkack
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The dependency of liquid He latent heat of evaporation on temperature shows a conspicuous maximum.
https://www.nist.gov/system/files/documents/srd/jpcrd551.pdf for
4He. Section 16, pages 1264-1266 on pages, 48-50 on pdf. From fig. 16.1 and table 16.3, the maximum is around 3,1 K and 94 J/mol. At lower temperatures, the latent heat drops sharply, though not to zero but 59,83 J/mol
3He has similar graph, though with lower heat of evaporation and lower temperature for maximum.

The drop of latent heat at higher temperatures is natural and common to liquids. With thermal expansion, the binding energy of liquid decreases; with increased vapour density, the binding energy of vapour increases and equalizes to the liquid binding energy at critical point.

What might be the reason for the drop of latent heat at lower temperature? I have not heard of it commented as any special property of liquid He.
Comment 5 at page 48 states that at low temperatures
L=L0+(5/2)RT
What is (5/2)R? Heat capacity of gas (the liquid´s being comparatively negligible)? Then which is the applicable one? He is monoatomic, so 3/2 would be constant volume, 5/2 constant pressure?
 
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  • #3
Lambda point does make a notch in 4He latent heat, but that´s a completely different issue. Looks like the issue is that of the heat content of gaseous vs. condensed phases... and all substances should have a drop of latent heat of evaporation at low temperatures.
 

1. What is latent heat in liquid helium?

Latent heat is the amount of energy required to change the state of a substance without changing its temperature. In liquid helium, it is the energy required to convert the liquid into a gas.

2. Why does the latent heat of liquid helium decrease at lower temperatures?

The decrease in latent heat at lower temperatures is due to the decrease in the density of liquid helium. As the temperature decreases, the helium atoms become more closely packed together, making it easier for them to escape into a gas state. This requires less energy, resulting in a decrease in latent heat.

3. How does the drop in latent heat affect the properties of liquid helium?

The decrease in latent heat at lower temperatures leads to a decrease in the heat capacity of liquid helium. This means that it takes less energy to raise the temperature of liquid helium at lower temperatures compared to higher temperatures.

4. Does the drop in latent heat have any practical applications?

Yes, the decrease in latent heat at lower temperatures is important for applications such as cryogenics. It allows for the efficient production of extremely low temperatures, making liquid helium a valuable resource in industries such as superconductivity and medical imaging.

5. Is the drop in latent heat unique to liquid helium?

No, the decrease in latent heat at lower temperatures is a common phenomenon in many substances. It is a result of the decrease in density and the decrease in energy required for a substance to change states as the temperature decreases.

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