Hello, I'm working on this Mathematica assignment, just basic tutorial-type stuff (you can ignore the details about pyrene, not important), and the fit on this function won't converge. Someone in my class said it converged fine, so I was wondering if anyone notices any errors in my work. Alternatively, can you think of any alternative ways to express the function?(adsbygoogle = window.adsbygoogle || []).push({});

Thanks!

1. The problem statement, all variables and given/known data

3. Formation and Decay of Pyrene Excimer in Solution

The traces for pyrene fluorescence (see Experiment 3) show a fast rise and a slower fall processes which correspond to a complex kinetic of the formation and decay of the pyrene excimer in solution. The evolution of the excimer fluorescence intensity I(t) in time t can be described by the following equation:

I(t) = -Ae^{-kat}+Be^{-kbt}

Data are provided in a file “emission_data” with time given in the first column, while the fluorescence intensity given in the second column.

REPORT:

(1) Find coefficients A, B, ka and kb. Estimate standard error and confidence levels for these parameters. Hint: see Mathematica help menu for function NonlinearModelFit.

(2) Provide plot of data with the superimposed fit function

2. Relevant equations

Mathematica knowledge

3. The attempt at a solution

See attached screenshot.

I can get 3/4 coefficients, but I don't know if they're correct due to the fourth one failing to converge, and I can't make the plot without all coefficients!

1. The problem statement, all variables and given/known data

2. Relevant equations

3. The attempt at a solution

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# Homework Help: Mathematica NonlinearModelFit

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