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Need Help! About resonance

  1. Feb 26, 2009 #1
    Question: Is a hybrid structure and a superposition the same thing? (I'm interested in the case of benzene)

    Read many sources but they were contradictory..

    Please help!
    Thanks!
     
  2. jcsd
  3. Feb 26, 2009 #2

    Ygggdrasil

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    No. Resonance hybrids represent real molecular orbitals that cannot be well represented by conventional chemistry notation. They are not superpositions of molecular orbitals. See the discussion below for more details.

    http://www.chemicalforums.com/index.php?topic=30853
     
  4. Feb 26, 2009 #3
    Ok, but does benzene have a superposition as well as a hybrid structure?
     
  5. Feb 27, 2009 #4

    Ygggdrasil

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    Superpositions of energy eigenstates normally only come into play when you electronically excite a molecule (for example, when the molecule is interacting with light).
     
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