How do I prove that the wave function R_{10}(r) is normalized?

  • Thread starter karkas
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In summary, the conversation is about proving that the function R_{10}(r) = \frac{2}{a_{0}^{3/2}}\cdot e^{-\frac{r}{a_0}} is normalized, using the equation \int_{-\infty}^{\infty} |\psi|^2 dV = 1. The attempt at a solution involves taking the integral of R_{10}(r) and leads to the result of 2/a_0^2 instead of 1. It is then suggested to use r²dr instead of just dr in the volume integral, which solves the problem. The person asking for help then requests more information on where this comes from.
  • #1
karkas
132
1

Homework Statement


Its simple, I've encountered this problem in Beiser's book and it doesn't seem right:

Prove that the function [tex]R_{10}(r) = \frac{2}{a_{0}^{3/2}}\cdot e^{-\frac{r}{a_0}} [/tex] is normalized.

Homework Equations


[tex]\int_{-\infty}^{\infty} |\psi|^2 dV = 1 [/tex]

The Attempt at a Solution


I figured it's simply just taking the integral
[tex]R_{10} (r)=\int^{\infty}_{0}( \frac{2}{a_{0}^{3/2}}\cdot e^{-\frac{r}{a_0}})^2dr = 1 [/tex]
but the result is not 1, it's [tex]2/a_0^2[/tex]
 
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  • #2
Don't you need r²dr instead of just dr?
(volume integral, spherical-polar coords.)
 
  • #3
Yes it appears that solves the problem, thanks!
 
  • #4
I would enjoy a pointer as to where this comes from exactly, maybe a link?

edit: just standard triple integration in 3 coordinates?
 
Last edited:
  • #5


To prove that the wave function R_{10}(r) is normalized, we must show that the integral of its square over all space is equal to 1. This can be expressed mathematically as:

∫∞0 |R_{10}(r)|^2 dr = 1

To solve this integral, we can use the substitution u = r/a_0, which transforms the integral into:

∫∞0 \frac{4}{a_0^3} e^{-2u} du = \frac{4}{a_0^3} ∫∞0 e^{-2u} du

Using the integral rule ∫ e^x dx = \frac{1}{n} e^x + C, we can solve for this integral and substitute back in for u:

\frac{4}{a_0^3} (-\frac{1}{2} e^{-2u}) \Big|_0^∞ = \frac{4}{a_0^3} (-\frac{1}{2} e^{-2r/a_0}) \Big|_0^∞ = \frac{4}{a_0^3} (-\frac{1}{2}) = \frac{2}{a_0^3}

This result shows that the square of the wave function is equal to 1, thus proving that R_{10}(r) is normalized.
 

What is a normalized wave-function?

A normalized wave-function is a mathematical function that describes the quantum state of a particle. It is a complex-valued function that satisfies the normalization condition, meaning that the integral of its absolute value squared over all space is equal to 1.

Why is normalization important for wave-functions?

Normalization is important because it ensures that the total probability of finding a particle in any location is equal to 1. This is a fundamental principle in quantum mechanics and allows for accurate predictions of the behavior of particles.

How is normalization achieved for a wave-function?

To normalize a wave-function, the integral of the absolute value squared of the function is calculated over all space. Then, the function is divided by the square root of this integral, resulting in a normalized wave-function with a total probability of 1.

What happens if a wave-function is not normalized?

If a wave-function is not normalized, it means that the total probability of finding a particle in any location is not equal to 1. This can lead to incorrect predictions and violates the fundamental principles of quantum mechanics.

Can any wave-function be normalized?

Not all wave-functions can be normalized. In order for a wave-function to be normalized, it must satisfy certain mathematical conditions, such as being square-integrable. If a wave-function does not satisfy these conditions, it cannot be normalized.

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