How to Determine the Number of Pi Bonds in a Molecule Using the MO Model?

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In summary, the number of pi bonds in a molecule is equal to 3 minus the "power" of p, or the hybridized bond formed. The answer of 4 in part b is only calculated from the 4 elements' bond, so the central O and C atom are not included in the calculation. Each single bond has one sigma bond, while each double bond has one sigma bond and one pi bond. The number of pi bonds is not always indicative of the degree of hybridization, but it is easier to count the number of double and triple bonds in the molecule.
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yecko
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Homework Statement


HunOeH0.png

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Homework Equations


MO model

The Attempt at a Solution


as far as i know, number of pi bond is equal to 3 - the "power" of p (the hybridized bond formed)
the answer "4" is only calculated from the 4 elements' bond in part b, so why the central O and C atom is not considered with calculation of pi bond? Thanks!
 
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Each single bond consists of one sigma bond. Each double bond consists of one sigma bond and one pi bond.
 
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Does that means the number of pi bond is independent to degree of hybridization?
Thanks!
 
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yecko said:
Does that means the number of pi bond is independent to degree of hybridization?
Thanks!
They are not independent as you generally need an unhybridized p-orbital to form a pi bond, but the number of unhybridized p-orbitals will not always be indicative of the number of pi bonds. It's much easier to simply count the number of double and triple bonds shown in the molecule.
 

What is the MO model?

The MO (molecular orbital) model is a theoretical model used to describe the electronic structure and bonding in molecules. It is based on the combination of atomic orbitals to form molecular orbitals.

How does the MO model explain the number of pi bonds?

The MO model explains the number of pi bonds by considering the overlapping of p orbitals. Each pi bond is formed by the overlap of two p orbitals, resulting in the formation of a pi molecular orbital.

What is the relationship between the number of pi bonds and bond strength?

The number of pi bonds is directly related to bond strength. As the number of pi bonds increases, the bond strength also increases. This is because the overlap of p orbitals creates a stronger bond than the overlap of s orbitals.

How does the number of pi bonds affect the geometry of a molecule?

The number of pi bonds can affect the geometry of a molecule by influencing the bond angles. Pi bonds are weaker than sigma bonds and therefore, they have a smaller influence on the molecular geometry. However, the presence of pi bonds can cause distortions in the overall shape of the molecule.

Can the MO model accurately predict the number of pi bonds in a molecule?

Yes, the MO model can accurately predict the number of pi bonds in a molecule. It takes into account the electronic structure of the atoms and the overlap of orbitals to determine the number of pi bonds in a molecule.

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