Organic Nomenclature - Benzenes

In summary, the basic structure of a benzene molecule is a hexagonal ring of six carbon atoms with alternating double and single bonds. Substituents on a benzene ring are named using the prefix "phenyl" followed by the name of the substituent. The terms ortho, meta, and para refer to the relative positions of substituents on a benzene ring. When there are multiple substituents on a benzene ring, they are numbered and the prefix "di-" or "tri-" is used. The suffix used for aromatic compounds in organic nomenclature is "-ene" or "-ene".
  • #1
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http://chemistry.boisestate.edu/people/richardbanks/organic/nomenclature/aromatic3.gif is called o-methylethylbenzene, why isn't it instead called o-ethylmethylbenzene? I thought it was alphabetical
 
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  • #2
IUPAC says it's alphabetical. In my experience both tend to be fine, people don't stick to that rule so closely.
o-ethyltoluene would work too.
 
  • #3


The naming of organic compounds follows a specific set of rules established by the International Union of Pure and Applied Chemistry (IUPAC). According to these rules, the parent chain (in this case, the benzene ring) should be the longest continuous chain of carbon atoms. The substituents (in this case, the methyl and ethyl groups) are then named in alphabetical order. In the case of o-methylethylbenzene, the methyl group is closer to the parent chain than the ethyl group, so it is named first. This follows the IUPAC rules for naming organic compounds and ensures consistency in the naming of compounds. Therefore, while it may seem more logical to name the compound as o-ethylmethylbenzene, the correct name according to IUPAC rules is o-methylethylbenzene.
 

1. What is the basic structure of a benzene molecule?

The basic structure of a benzene molecule is a ring of six carbon atoms, each bonded to one another and to a hydrogen atom. This arrangement is known as a hexagonal ring and is often depicted as a flat hexagon with alternating double and single bonds between the carbon atoms.

2. How are substituents named on a benzene ring?

Substituents on a benzene ring are named using the prefix "phenyl" followed by the name of the substituent. For example, a benzene ring with a methyl group attached would be named "methylbenzene" or "phenylmethane".

3. What is the difference between ortho, meta, and para positions on a benzene ring?

These terms refer to the relative positions of substituents on a benzene ring. Ortho refers to substituents that are directly adjacent to one another, meta refers to substituents that are separated by one carbon atom, and para refers to substituents that are directly opposite to one another on the ring.

4. How are multiple substituents named on a benzene ring?

When there are multiple substituents on a benzene ring, they are numbered in order of priority (determined by the alphabetical order of their prefixes) and the prefix "di-" or "tri-" is used to indicate multiple substituents of the same type. For example, a benzene ring with two methyl groups and one chlorine atom would be named "1,2-dimethyl-3-chlorobenzene".

5. What is the suffix used for aromatic compounds in organic nomenclature?

The suffix used for aromatic compounds is "-ene" or "-ene" to indicate the presence of a benzene ring. For example, benzene itself is called "benzene", while a compound with a benzene ring and a double bond would be named "benzene-ene" or "benzeneene".

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