What is the reason behind fermions being unable to share the same quantum state?

In summary, the Pauli principle states that identical fermions must have an anti-symmetric wavefunction, leading to the rule that two fermions cannot occupy the same single-particle state. This is due to the spin-statistics theorem, which ultimately boils down to the fact that nature does not differentiate between identical particles. The rule can also be expressed as L+S being even in the center of mass frame, leading to the conclusion that two electrons with different orbital and spin quantum numbers cannot occupy the same state. This rule can be found in various sources, such as the classic Jacob & Wick paper and the book "Elementary Theory of Angular Momentum".
  • #1
Higgsono
93
4
What is the explanation for the case that fermion's can't occupy the same quantum state? Is there some logic behind this or is it just observation?
 
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  • #2
The short answer is that the Pauli principle states that a valid state for identical fermions must be anti-symmetric with respect to the exchange of two particles. You can't construct an anti-symmetric state where two fermions are in the same single-particle state.

As to why the Pauli principle applies, you have to look up the spin-statistics theorem. Ultimately, the answer is "because Nature is that way."
 
  • #3
Ultimately, the reason is that nature doesn't care which particle a potential observer thinks is which. A similar rule applies to bosons. The rules are usually expressed as symmetry or anti-symmetry of the wavefunction depending on spin. An alternative expression of the rule (and one that relates directly to observables) is that L+S must be even in the CM frame (equal and opposite momentum) for any pair of identical particles, where L is the net orbital angular momentum and S is the net spin angular momentum. In a frame where the particles have equal and parallel momentum, then the rule becomes that S must be even and, in the case of electrons, this means S=0 so they must have opposite spin. In the case of atomic electrons, where it becomes the Pauli rule, it is stated as "no two electrons can occupy the same state" because if all other quantum numbers are identical then the spins must be opposite so they sum to 0 (with the corollary that if the spins are the same, then the states must differ in some other way).
 
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  • #4
mikeyork said:
UAn alternative expression of the rule (and one that relates directly to observables) is that L+S must be even in the CM frame (equal and opposite momentum) for any pair of identical particles, where L is the net orbital angular momentum and S is the net spin angular momentum.
Do you have any reference for this statement? Does it mean that having two electrons, one with ##l=0,m_l=0,m_s=1/2## and the other ##l=2,m_l=2,m_s=1/2## (so ##L=2##, ##S=1##) is not allowed?
 
  • #5
DrClaude said:
Do you have any reference for this statement? Does it mean that having two electrons, one with ##l=0,m_l=0,m_s=1/2## and the other ##l=2,m_l=2,m_s=1/2## (so ##L=2##, ##S=1##) is not allowed?
Good question! The L+S rule comes from SU(2) couplings given the usual anti-symmetry. Off the top of my head I think the answer to your question is that you can't get those two specific orbital states in the CM frame because of the spatial symmetry relating the angular co-ordinates (their momenta point in opposite directions). So, for instance you could have l1 = l2 = 1 and then the L=1 state would require s1 = s2. From memory I think the original rule comes from the classic Jacob & Wick* paper on helicity states, but you can also find it in my spin-statistics papers (which I haven't linked because they are not accepted mainstream for other reasons). PM me if you want further information.

*M. Jacob and G. Wick, “On the general theory of collisions for particles with spin,” Annals Phys. 7 (1959) 404–428. (I can't locate my copy at this moment but, IIRC, they give the partial wave analysis of identical particle scattering in the CM frame.)

Later edit: Also check out Rose "Elementary Theory of Angular Momentum", Chapter XII, section 38 ("Identical Particles in L-S coupling").
 
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1. What is the Pauli Exclusion Principle?

The Pauli Exclusion Principle is a fundamental principle in quantum mechanics that states that no two identical fermions (particles with half-integer spin) can occupy the same quantum state simultaneously. This means that in a system, each fermion must have a unique set of quantum numbers.

2. Who proposed the Pauli Exclusion Principle?

The Pauli Exclusion Principle was first proposed by Austrian physicist Wolfgang Pauli in 1925. It was later refined by Enrico Fermi in 1926.

3. What is the significance of the Pauli Exclusion Principle?

The Pauli Exclusion Principle is significant because it explains many important properties of matter, such as the periodic table of elements and the stability of atoms. It also plays a crucial role in understanding the behavior of electrons in atoms and molecules.

4. Can the Pauli Exclusion Principle be violated?

No, the Pauli Exclusion Principle is a fundamental law of nature and has been experimentally verified numerous times. It is not possible for fermions to violate this principle.

5. How does the Pauli Exclusion Principle apply to electrons?

Electrons, as fermions, must follow the Pauli Exclusion Principle. This means that in an atom, each electron occupies a unique quantum state, and no two electrons can share the same set of quantum numbers. This principle also explains the arrangement of electrons in different energy levels and orbitals within an atom.

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