Permanganate Ion and Glucose

[danago]

Hi.
In class recently, we performed a reaction where we added potassium permanganate solution to a solution of sodium hydroxide, followed by a few grains of glucose. The resulting solution was green for a short time, and then quickly went to an orange colour.

Im not very sure about what happened in this reaction. I think that the permanganate ion was reduced to an MnO₄^2- ion, which is the reason for the green colour, but why did it then go orange? And what is the purpose of the glucose? Was it the reducing agent?

Thanks in advance,
Dan.

 

[TeethWhitener]

Im not very sure about what happened in this reaction. I think that the permanganate ion was reduced to an MnO42- ion, which is the reason for the green colour

This sounds right. Here's a Pourbaix diagram for manganese:
https://www.wou.edu/las/physci/ch462/pourbxmn.gif

but why did it then go orange?

My guess is that the Mn(VI) in the green MnO₄^2- was reduced to brown solid MnO₂.

And what is the purpose of the glucose? Was it the reducing agent?

Yes. Glucose is a reducing sugar.

EDIT: To be completely explicit: with a solution of KMnO₄, you start way up in the purple region of the Pourbaix diagram. When you add NaOH, that pushes you toward the right of the diagram. Then adding glucose pushes you downward, presumably through the green region into the brown and red regions.