Uncovering the Mystery of Wave Function Symmetry

In summary: You are missing the point of my answers ... for a given n (i.e. a given frequency), the only difference between a sine and a cosine is a phase shift of \frac{\pi}{2}. So, whether or not a function is a sine or a cosine depends on your choice of origin, which you changed when you changed your coordinates. Now, the question you have to answer is what happens to the phase of the sine waves describing the eigenstates in your initial coordinate system when you shift to the new coordinate system. I suggest that you work it out on paper if it is not clear to you ...Oh... I did miss the point. Of course that depends
  • #1
noamriemer
50
0
Hello again!

Say I have a potential well, between 0 and a. I also know how the wave function looks like for (t=0):
[itex] \psi(x,0)= \frac {2bx} {a} [/itex] for [itex] 0<x<\frac {a} {2} [/itex]
and
[itex] \psi(x,0)= 2b(1- \frac {x} {a} ) [/itex] for [itex] \frac {a} {2} <x<a [/itex]

Now, I wish to find the wave function of a general time, t.
I know I need to find symmetry. Therefore I move the x axis:
[itex] x\rightarrow x', x'\equiv x-\frac {a} {2} [/itex]

So now I have the same well, only symmetrical.

That means:

[itex] \varphi_n =\sqrt {\frac {2} {a} } sin(\frac {\pi lx'} {a}) \rightarrow l=2n
\varphi_n =\sqrt {\frac {2} {a} } cos(\frac {\pi lx'} {a}) \rightarrow l=2n+1 [/itex]

For the question before the axis transition, I know I have to look for a sin- solution.
But now, when I have this symmetry, I should look for a solution which vanishes at x=-a/2 instead of x=0

Meaning, the cosine must stay. But in this problem's solution, I see that the sine stays...
why is that so?
Thank you!
 
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  • #2
noamriemer said:
Hello again!

Say I have a potential well, between 0 and a ...
Meaning, the cosine must stay. But in this problem's solution, I see that the sine stays...
why is that so?
Thank you!

I assume you mean outside of [0, a], the potential is infinity (an infinite potential well).

If that's the case, the wave function must vanishes at x=0 and x=a. [itex]\varphi_n = \sin \frac{\pi n x}{a}[/itex] do this, [itex]\varphi_m = \cos \frac{\pi m x}{a}[/itex] do not.
 
  • #3
mathfeel said:
I assume you mean outside of [0, a], the potential is infinity (an infinite potential well).

If that's the case, the wave function must vanishes at x=0 and x=a. [itex]\varphi_n = \sin \frac{\pi n x}{a}[/itex] do this, [itex]\varphi_m = \cos \frac{\pi m x}{a}[/itex] do not.

Yes. of course. What I don't understand is why- if I change the axis so the problem becomes symmetric, do I still use sine instead of cosine.

For this axis, the wave function has to be zero for a/2 and -a/2, instead of 0 and a...
 
  • #4
noamriemer said:
Yes. of course. What I don't understand is why- if I change the axis so the problem becomes symmetric, do I still use sine instead of cosine.

For this axis, the wave function has to be zero for a/2 and -a/2, instead of 0 and a...

You just did a mathematical trick to re-define your coordinates .. nothing about the problem has actually changed. If you transform back to your original coordinates, all of your wavefunctions will be sine waves. As to why you still have some sine solutions in the new coordinates, look closely at the conditions where the wavefunctions are sine solutions. Does that suggest anything to you?
 
  • #5
Thank you... but no... it doesn't suggest anything. I thought that there can't be a superposition of the two functions under such assumptions...
 
  • #6
noamriemer said:
Thank you... but no... it doesn't suggest anything. I thought that there can't be a superposition of the two functions under such assumptions...

You only have sine functions for *even* values of n. Where are the nodes for such a sine wave? How does that match up with your boundary conditions? What if you tried to use cos functions for the even values of n?
 
  • #7
Why should it matter?

once I know how the wave function looks like for t=0 I know it had collapsed into this form. Therefore- If I had sine function- it will not change...

Or did I misunderstood you?
Thank you so much for your enlightening answers...
 
  • #8
noamriemer said:
Why should it matter?

once I know how the wave function looks like for t=0 I know it had collapsed into this form. Therefore- If I had sine function- it will not change...

Or did I misunderstood you?
Thank you so much for your enlightening answers...

You are missing the point of my answers ... for a given n (i.e. a given frequency), the only difference between a sine and a cosine is a phase shift of [itex]\frac{\pi}{2}[/itex]. So, whether or not a function is a sine or a cosine depends on your choice of origin, which you changed when you changed your coordinates. Now, the question you have to answer is what happens to the phase of the sine waves describing the eigenstates in your initial coordinate system when you shift to the new coordinate system. I suggest that you work it out on paper if it is not clear to you ...
 
  • #9
Oh... I did miss the point. Of course that depends on a phase only. I know that. I just can't get a clear answer about general things I don't understand.

But writing the questions (and, of course, reading the answers) make everything more clear...
Thank you so much!
 

1. What is wave function symmetry?

Wave function symmetry refers to the behavior of a wave function under certain transformations, such as spatial reflections or rotations. This symmetry is related to the physical properties of a system and can provide insights into its behavior and characteristics.

2. Why is wave function symmetry important?

Wave function symmetry is important because it can help us understand the behavior of quantum systems and predict their properties. It also plays a crucial role in determining the selection rules for allowed transitions between energy states in atoms and molecules.

3. How do scientists uncover the mystery of wave function symmetry?

Scientists use mathematical tools and theories, such as group theory and representation theory, to analyze the symmetries of wave functions and understand their implications for physical systems. They also conduct experiments and simulations to test and validate their findings.

4. What are some real-world applications of wave function symmetry?

Wave function symmetry has a wide range of applications in various fields, including chemistry, materials science, and quantum computing. It can help predict the properties of new materials, design more efficient chemical reactions, and develop advanced quantum algorithms.

5. Are there different types of wave function symmetry?

Yes, there are different types of wave function symmetry, such as spatial symmetry, time-reversal symmetry, and spin symmetry. Each type of symmetry has its own set of rules and implications for physical systems, and they can also interact with each other to create more complex symmetries.

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