Potential Energy of an Atom Due to Its Charge Distribution

In summary, the potential energy of a nucleus due to its charge is (3Z^2.e^2)/(20.pi.epsilon-0.a). If the charge was spread uniformly over the surface of the nucleus, the potential energy would be (Z^2.e^2)/(24.pi.epsilon-0.a). The mistake in the initial calculation was not considering the electric field at all points in space.
  • #1
Hoofbeat
48
0
Could someone help me with this:

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Q. The nucleus of an atom can be considered to be a charge of +Ze uniformly distributed throughout a sphere of radius a. Show that the potential energy of a nucleus due to its charge is (3Z^2.e^2)/(20.pi.epsilon-0.a). What would the potential energy be if the charge was spread uniformly over the surface of the nucleus.
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I used Gauss' law and spherical coordinates (we can ignore all components other than R due to symmetry) to give the electric field (radial component):

Er = +Ze/(4.pi.epsilon-0.a^2)

Energy Density = 1/2.Epsilon-0.E^2

But we want total energy, thus:

Energy = 1/2.Epsilon-0.E^2.Volume

Energy = (Z^2.e^2)/(24.pi.Epsilon-0.a)

However, this is clearly wrong. Could someone tell me what I'm doing wrong?! :frown: Thanks
 
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  • #2
The electric field Er you computed is the electric field at the surface of the nucleus. But you want to find the total potential energy of the nucleus, which is the integral:

[tex] \int_{whole space} 1/2 \epsilon_0 E^2 dV [/tex]

So you need to know the E every in space (use Gauss' law).
 
  • #3
Thanks, I've now managed to solve the problem :D
 

1. What is potential energy of an atom?

Potential energy of an atom is the energy an atom possesses due to its position or arrangement in a system. It is a type of energy that can be stored and later converted into other forms of energy.

2. How is potential energy related to an atom's position?

The potential energy of an atom is directly related to its position in a system. As an atom's position changes, its potential energy also changes. This is because the distance between atoms and their arrangement in a system determines the amount of potential energy they possess.

3. What factors affect an atom's potential energy?

An atom's potential energy is affected by its position, the forces acting on it, and the interactions with other atoms in a system. The type and strength of the force, as well as the distance between atoms, can all impact an atom's potential energy.

4. Can an atom have both kinetic and potential energy?

Yes, an atom can have both kinetic and potential energy at the same time. When an atom is in motion, it possesses kinetic energy, and when it is at rest but has the potential to move, it has potential energy.

5. How is potential energy of an atom important in chemical reactions?

The potential energy of an atom plays a crucial role in chemical reactions. During a reaction, atoms rearrange and form new bonds, which leads to a change in their potential energy. This energy change is what drives the reaction and determines its outcome.

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