What causes the tilt angle of a precessing proton to change in a magnetic field?

In summary, the tilt angle of a precessing proton in a magnetic field is determined by the presence of friction forces, which cause its average magnetic moment to align with the field over time. This is different from a spinning top, which will maintain its original tilt angle assuming no friction.
  • #1
dangus
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What determines the tilt angle of a precessing proton in a magnetic field? Is it a constant the assuming no additional magnetic forces?

In an NMR a perpendicular magnetic field is applied which rotates the precessing magnetic moment into the X-Y plane. After this perpendicular magnetic pulse is removed the magnetic moment returns back to its original tilt angle. This runs counter to the spinning top analogy that is often used for the precessing proton. My understanding is that the tilt angle of a precessing top will remain fixed assuming no friction. So If I took a spinning top precessing at angle θ1 and then applied a force to increase the tilt angle to θ2, when that force is removed the top will continue to precess at this new tilt angle θ2. Is this all correct? Why is the proton different from the top in this case?
 
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  • #2
Hello dangus,

one way to understand the gradual alignment of the magnetic moment with the external field is in terms of suspended eternally-spinning top in uniform gravitational field, whose precession is damped by friction forces in the suspension or by the air.

In the presence of friction, things tend to lose as much energy as possible. In this case the state of lowest energy is such that magnetic moment loses all its " precession energy " (I do not know whether there really is such thing, but seems to work in this case).

With protons, because friction forces are present too, in the course of time, their average magnetic moment leaves the lateral plane and tends to be aligned with the field (individual moments can fluctuate around).
 

1. What is the concept of precessing protons in NMR?

The concept of precessing protons in NMR (Nuclear Magnetic Resonance) is based on the principle that atomic nuclei with an odd number of protons or neutrons have a magnetic moment. In an external magnetic field, these protons will align with the field and precess around it, similar to the way a spinning top precesses. This precession can be detected and measured using radiofrequency pulses, providing information about the chemical structure of a substance.

2. How does NMR work to provide information about a substance?

NMR works by applying a strong magnetic field to a sample, causing the protons in the sample to align with the field. Radiofrequency pulses are then applied, causing the protons to flip or precess. The frequency of the precession is dependent on the chemical environment of the protons, providing information about the structure of the sample. This information is then processed and displayed as a spectrum, which can be analyzed to identify the compounds present in the sample.

3. What is the role of precessing protons in medical imaging?

In medical imaging, precessing protons are used in a technique called MRI (Magnetic Resonance Imaging). A strong magnetic field is applied to the body, causing the protons in the body's tissues to align with the field. Radiofrequency pulses are then applied, causing the protons to emit signals that can be detected and processed to create detailed images of the body's tissues. This allows for non-invasive imaging and diagnosis of various medical conditions.

4. Can precessing protons be used in other applications besides NMR and MRI?

Yes, precessing protons can be used in other applications such as quality control in the food and pharmaceutical industries. NMR can be used to analyze the chemical composition of food and drugs, ensuring their safety and quality. It can also be used in material science to study the structure and properties of various materials, such as polymers and alloys.

5. What are the limitations of using precessing protons in NMR?

One of the main limitations of using precessing protons in NMR is the need for a strong and uniform magnetic field. This can be challenging and expensive to achieve, especially in portable or handheld NMR devices. Additionally, the technique is limited to samples containing nuclei with an odd number of protons or neutrons, which may not provide a complete picture of a substance's chemical structure. Care must also be taken to prevent interference from external magnetic fields, which can affect the accuracy of the results.

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