Understanding Work in Quasistatic Expansion and Compression of a Gas

In summary: That is not correct. Work is the change in energy. In this situation the gas is doing work on the piston, but the work is negative because the piston is moving inward.
  • #1
PhysicForFun
6
0

Homework Statement


Given the cycle shown below, what is the total work done by the gas in the cycle?
grid.png


Homework Equations


ΔU = ΔQ + ΔW
W = PΔV

The Attempt at a Solution


W = 0
W = PΔV = 2 x (6-1) = 10
W = (1/2)bh = (1/2) (5-2) (6-1) = 7.5

W = W + W + W = 0 + 10 + 7.5 = 17.5
Since the volume is increasing, Work is positive.

It says I am wrong. So any help would be appreciated. I think I might know the issue, but want feedback.
 
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  • #2
Your expression W = PΔV is the one to use
This is an area on the graph...the enclosed area of the cycle
Your answer of 7.5 looks correct... you must include units
 
  • #3
Welcome to PF, PhysicForFun! :smile:

You red work should be negative.
And your green work should be the entire area under the green line, meaning a total of 17.5.

The actual total work is the area of the triangle.
 
  • #4
So the fact that is says work done by the gas isn't important? Am I reading too much into it?

The gas does work when the volume expands. And the externalsystem does work whenever it compresses right?

I might just be getting too caught up in wording. But I am curious. Thanks for the help so far though.
 
  • #5
Indeed, the gas does work when the volume expands.
But more specifically, the gas does negative work when the volume compresses.

It may be a bit counter-intuitive, but that is how work is defined.
 
  • #6
Ok thank you for explaining. It makes sense, but it doesn't seem logical. Regardless I will just accept it.
 
  • #7
Imagine that the gas is confined in a cylindrical container fitted with a movable piston of area A. Suppose the gas is in equilibrium and its pressure is P. Then the forces acting on the piston must cancel. The gas exerts an outward force equal to F(gas)=PA. Then the external force must be F(ext)=-F(gas).
Imagine that the external force is just a bit smaller than the external force, so the gas expands, but the expansion is so slow that the kinetic energy of the piston is negligible. In this case the total work done on it is zero. The total work is equal to the work of the gas and the work of the external agent, and it is zero in a quasistatic expansion. dW=dW(gas)+dW(ext)=0

The work is displacement times force. When the gas expands, the force points outward and the piston moves outward by a small amount, dx. The work of the gas is positive W(gas)=F(gas)dx>0.

The total work is zero,

dW(gas)+dW(ext)=0

that means dW(external)=-dW(gas)..

This is logical as the external force points inward, while the piston displaces outward. Force is opposite to the displacement, so the external work is negative.

Now suppose that the force of the gas is just a bit smaller so the external force overcomes the force of the gas. Then the gas is compressed, the piston moves inward while the gas exerts an outward force on the piston. In this case, the work of the gas is negative. At the same time, the external work is positive, as the piston moves inward and the external force also points inward.

You can conclude that in case of quasystatic expansion or compression of the gas the work of the gas is opposite to the external work.

W(gas)=-W(external).

The force the gas exerts on the piston is F(gas)=PA, and the work done when the piston displaces by dx is dW=(PA)dx. Adx is the change of volume. So the work of the gas is dW(gas)=PdV, positive during expansion (dV>0) and negative during compression (dV<0).

ehild
 

1. What is a Pressure vs. Volume graph?

A Pressure vs. Volume graph, also known as a PV diagram, is a representation of the relationship between pressure and volume of a gas at different states. It is a common tool used in thermodynamics to analyze the behavior of gases under different conditions.

2. How is pressure and volume related in a PV diagram?

In a PV diagram, pressure and volume are inversely related. This means that as pressure increases, volume decreases and vice versa. This relationship is known as Boyle's law and is represented by a hyperbolic curve on the graph.

3. What information can be obtained from a Pressure vs. Volume graph?

A PV diagram can provide information about the state of a gas, such as its pressure, volume, and temperature. It can also show the changes in these properties as the gas undergoes different processes, such as isothermal, adiabatic, and isobaric processes.

4. How is work calculated from a Pressure vs. Volume graph?

The work done on or by a gas can be calculated from a PV diagram by finding the area under the curve. This is known as the area of the work loop and is equal to the work done by the gas during a given process.

5. What factors can affect the shape of a Pressure vs. Volume graph?

The shape of a PV diagram can be affected by various factors, including the type of gas, temperature, and external pressure. Additionally, any changes in the state of the gas, such as phase transitions or chemical reactions, can also alter the shape of the graph.

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