Problems related to Maxwell relations

In summary, the problem requires finding the mathematical constraint for α and β in the given system entropy equation, using the conditions of (∂T/∂U) < 0, (∂P/∂V) < 0, and (∂μ/∂N) > 0. The attempt at a solution involved using Maxwell relations and the equation dF = SdT - PdV + μdN, but the solution is not yet available.
  • #1
Mayan Fung
131
14

Homework Statement


Given the entropy of a system :
$$ S = AU^αV^βN^{1-α-β} $$
The problem requires me to write
$$ (\frac{∂T}{∂U})_{V,N} > 0,  (\frac{∂P}{∂V})_{U,N} < 0, (\frac{∂μ}{∂N})_{U,V} > 0$$
to find the mathematical constraint of α and β

Homework Equations


dU = TdS - PdV + μdN

The Attempt at a Solution


Actually, I don't quite understand the rationale behind Maxwell relations.
I tried to write
dF = SdT - PdV + μdN
I can then get
$$ (\frac {∂T} {∂F})_{V,N}$$
but I just don't know how to transform the variable. Can anyone give me an idea of these kind of problems. Thanks!
 
  • #3
This is actually a bonus question in my HW. It wrote something but I think they are wrong. The solution should be ready in the coming few days. I will share the ideas once it is released.
 
  • #4
you can check it.http://odysriwo8.bkt.clouddn.com/wo.PNG
 
  • Like
Likes Mayan Fung
  • #5
Thanks! I will try it!
 

1. What are Maxwell relations?

Maxwell relations are a set of four equations that relate the partial derivatives of thermodynamic properties, such as temperature, pressure, and volume, to each other.

2. Why are Maxwell relations important?

Maxwell relations are important because they allow us to calculate one thermodynamic property from another, making it easier to analyze and understand complex systems.

3. What problems can arise from using Maxwell relations?

Some problems that can arise from using Maxwell relations include mathematical inconsistencies, incorrect assumptions about the system, and the neglect of higher-order effects.

4. Can Maxwell relations be applied to all thermodynamic systems?

No, Maxwell relations are only applicable to systems that can be described by a single, continuous thermodynamic potential.

5. How can Maxwell relations be used to solve practical problems?

Maxwell relations can be used to solve practical problems by providing a framework for analyzing and understanding thermodynamic systems, and by allowing us to calculate unknown properties from known ones.

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