1. Limited time only! Sign up for a free 30min personal tutor trial with Chegg Tutors
    Dismiss Notice
Dismiss Notice
Join Physics Forums Today!
The friendliest, high quality science and math community on the planet! Everyone who loves science is here!

Q in crystal field theory

  1. Oct 31, 2008 #1
    at crystal field stabilization in strong field case
    d4 CFSE=-16Dq+p
    d5 CFSE=-20Dq+2p
    d6 CFSE=-24Dq+2p
    d7 CFSE=-18Dq+p

    d8 CFSE=-12Dq
    it was shuld be +3P and +4 P
    why it be +p,2p,2p,p ???
     
  2. jcsd
  3. Nov 1, 2008 #2

    GCT

    User Avatar
    Science Advisor
    Homework Helper


    Why do you believe that it should be + 3 and + 4? What equation are you using?
     
  4. Nov 6, 2008 #3
    my Q explain why the CFSE =-24Dq+2p at d6 not =-24Dq+3p?
    like u see in fig. if we put the 6`th electron we have 3 paring set so we was should add 3p to the CFSE why we count them as 2P?
    2628rbc.jpg
     
  5. Nov 6, 2008 #4

    GCT

    User Avatar
    Science Advisor
    Homework Helper

    You are right for this case where its Octahedral , scroll the link to page 9

    http://www.chemistry.ucsc.edu/~tholman/Chem151A/LectureNotes/Week2.pdf [Broken]

    Is this an Octahedral complex? Also did they mention a specific metal ligand complex ; sometimes an LS becomes HS should the actual CFSE is found to be positive with the incorporation of the pairing energy?
     
    Last edited by a moderator: May 3, 2017
Know someone interested in this topic? Share this thread via Reddit, Google+, Twitter, or Facebook




Similar Discussions: Q in crystal field theory
  1. Crystals of Nickel? (Replies: 5)

  2. Crystal Field Model (Replies: 1)

  3. Structure of crystals (Replies: 2)

Loading...