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Quantum Chemistry: Theory based questions
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[QUOTE="TeethWhitener, post: 4893895, member: 511972"] 1. Exactly. The potential curve asymptotically approaches the bond dissociation energy. 2. Weaker force constant = weaker bond, so as k goes to zero, this is the limit of no bond/no interaction. For the particle in a box, as the box gets bigger, again, you get a limit of no interaction. Essentially, the limiting case in both instances is that of a free particle (V(x)=0 for all x), where the zero point energy is zero. 3. This is just a language thing. For many equations in statistical mechanics, you'll have to know the degeneracy of an energy level, and in this case, if the level is nondegenerate, then the degeneracy = 1. But in general, if degeneracy = 1, we typically say the energy level is nondegenerate. The two terms are synonymous [/QUOTE]
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