Unlocking Quantum Numbers for Lithium Atom

In summary, Lithium's third electron in the lowest energy state has the quantum numbers {2,0,0,+1/2} and {2,0,0,-1/2}. The set of quantum numbers is motivated by the first shell being full, the s orbital of Lithium, and the preference for filling the m{s} +1/2 state before the m{s} -1/2 state.
  • #1
KingBigness
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Homework Statement



Lithium has an atomic number Z = 3. Two of its electrons have the quantum numbers {n, L, m{l}, m{s}} = {1,0,0,+1/2} and {1,0,0,-1/2}. Write down the corresponding set of quantum numbers for the third electron in the lowest energy state of the Li atom. Briefly explain the factors motivating the set of quantum numbers

Homework Equations


The Attempt at a Solution



Haven't done quantum numbers in a while.

The first shell is full so n=2. It is Lithium so it is still in the s orbital so l = 0
Firstly is this correct?

Now is where I get a little confused. Do the electrons have a preference when it comes to the m{s} numbers? Does it prefer to fill m{s} +1/2 before -1/2

My final answer for this question is (2,0,0,+1/2) is this correct?

Thank you for your time.
 
Last edited:
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  • #2
n=2, L=m(l)=0 should be correct for the reasons you have outlined above.
If you are being asked for the corresponding Set(!) of quantum numbers I believe you want to include both the spin-up and spin-down states in your answer.
 

1. What is a quantum number?

A quantum number is a numerical value that describes the energy levels and sublevels of an electron in an atom.

2. How many quantum numbers are associated with a lithium atom?

A lithium atom has four quantum numbers: the principal quantum number, the angular momentum quantum number, the magnetic quantum number, and the spin quantum number.

3. What is the significance of unlocking quantum numbers for a lithium atom?

Unlocking quantum numbers for a lithium atom allows us to better understand the energy levels and electron configurations of the atom, which can help us predict its chemical and physical properties.

4. How are quantum numbers for a lithium atom determined?

The first three quantum numbers (principal, angular momentum, and magnetic) are determined by the atom's energy level and sublevel, while the spin quantum number is determined by the spin of the electron.

5. Can quantum numbers for a lithium atom change?

Yes, quantum numbers for a lithium atom can change when the atom undergoes a change in energy level or sublevel, or when an electron is added or removed from the atom.

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