Hydrofluoric Acid + Silicon Dioxide Reaction Explained

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In summary, the conversation discusses the reaction between gaseous hydrofluoric acid and solid silicon dioxide. The resulting products after a double replacement are water and silicon fluoride. However, there are concerns about the validity of this reaction and questions arise about the number of valence electrons in silicon and the nature of the reaction (solution vs. solid). One participant also mentions struggling with this type of content and suggests memorization of rules. Another participant offers a possible answer to the second question, stating that silicon would have a 4+ charge since it is a solid and not an ion.
  • #1
hola
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Gaseous hydrofluoric acid reacts with solid silicon dioxide.
My work (did a double replacement):
HF+SiO2------>H2O+SiF

But this doesn't look right. Why?
1. It looks wierd.
2. How much valence electrons is Si supposed to have?
3. We're not dealing with solutions.


Anyone know the answer?
 
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  • #2
ohhh man i do really bad in these. You pretty much have to memorize lots of rules.
I can answer #2 though, since O = -2 and the substance is a solid, then the compound is not an ion thus Si being 4+ . Or...just count from left to right in periodic table. Noting that Si was the cation.
 
  • #3


I can offer an explanation to the concerns raised. Firstly, the reaction between hydrofluoric acid and silicon dioxide is a neutralization reaction, not a double replacement reaction. This is because hydrofluoric acid is a strong acid and silicon dioxide is a weak base, so the products will be a salt (SiF) and water (H2O). The correct balanced equation is:

2HF + SiO2 → SiF4 + 2H2O

Secondly, the reason why it may look "weird" is because the products are in gas and liquid form, rather than solid. This is due to the high reactivity of hydrofluoric acid, which readily dissociates into a gas at room temperature. The SiF4 gas may also be colorless, making it difficult to observe the reaction.

Regarding the valence electrons of silicon, it has four valence electrons and can form four covalent bonds. In this reaction, it forms covalent bonds with four fluorine atoms, resulting in the formation of SiF4.

Lastly, while we are not dealing with solutions, this reaction can still occur in both liquid and solid states. The reaction between gaseous hydrofluoric acid and solid silicon dioxide occurs at high temperatures and pressures, making it more relevant for industrial processes rather than laboratory experiments.

In conclusion, the correct balanced equation for the reaction between hydrofluoric acid and silicon dioxide is 2HF + SiO2 → SiF4 + 2H2O. This is a neutralization reaction that occurs at high temperatures and pressures, resulting in the formation of a gas and liquid product.
 

1. What is the chemical equation for the reaction between hydrofluoric acid and silicon dioxide?

The chemical equation for the reaction between hydrofluoric acid (HF) and silicon dioxide (SiO2) is HF + SiO2 → SiF4 + H2O.

2. How does the reaction between hydrofluoric acid and silicon dioxide occur?

The reaction between hydrofluoric acid and silicon dioxide occurs through a process called acid-base neutralization. The hydrogen ions in the hydrofluoric acid neutralize the hydroxide ions in the silicon dioxide, producing water and a salt, silicon tetrafluoride.

3. What are the properties of the products of the hydrofluoric acid and silicon dioxide reaction?

The two products of the reaction, water and silicon tetrafluoride, have very different properties. Water is a liquid at room temperature, odorless, and has a pH of 7. Silicon tetrafluoride is a gas at room temperature, has a pungent odor, and is highly corrosive and toxic.

4. What are the uses of the hydrofluoric acid and silicon dioxide reaction in industry?

The reaction between hydrofluoric acid and silicon dioxide is commonly used in industries such as glass manufacturing, electronics, and chemical production. It is used to etch and clean glass and silicon surfaces, as well as to produce various chemicals such as fluorine compounds and silicon tetrafluoride.

5. Are there any safety concerns when working with hydrofluoric acid and silicon dioxide?

Yes, there are several safety concerns when working with hydrofluoric acid and silicon dioxide. Hydrofluoric acid is a highly corrosive and toxic substance, and can cause severe burns and tissue damage upon contact. It is also highly reactive and can release toxic gases when mixed with certain substances. Adequate safety precautions, such as wearing protective gear and working in a well-ventilated area, should always be taken when handling these chemicals.

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