Mole: Avogadro's Number & Its Discovery

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In summary, the number of atoms in one mole is defined as 6.022*10^23, and this value was first determined by Loschmidt in 1865. This number was named after Avogadro, but he did not discover it. The original definition of one mole was based on the number of atoms in 1g of hydrogen gas, and this was chosen because 1g is a fundamental unit in the cgs system. However, there is no derivation for why 1 mole is equivalent to 6.022*10^23 atoms, as it is purely empirical and based on the arbitrary definition of the gram.
  • #1
akashpandey
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Why there is
1mole⇒6.022*1023 atom.
Why there is not another number.
How avogrado find that number exactely correct at that time where there was no instuments.
 
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  • #2
Avogadro did not find that number, it was only named after him. It's approximate value was first determined by Loschmidt in 1865:
http://books.google.de/books?id=ppEAAAAAYAAJ&pg=PA395#v=onepage&q&f=false
One mole was first defined as the number of atoms in 1g of hydrogen gas. As 1g is a fundamental unit in the cgs system, which is until today the preferred unit system in theoretical physics, this setting seems quite reasonable.
 
  • #3
But why
1 mole ⇒6.022*1023 atoms is their any derivation for it.
 
  • #4
It is the definition of the gram which is arbitrary and the number of atoms in one mole is purely empirical. The original definition of the gram was the mass of 1 cubic centimetre of water. At that time (end of the 18th century), one had no idea about the number of molecules that this amount might contain.
 

What is Avogadro's Number and why is it important?

Avogadro's Number, also known as the Avogadro constant, is a fundamental physical constant that represents the number of particles in one mole of a substance. This number is approximately 6.022 x 10^23 and is important because it allows scientists to easily convert between the mass of a substance and the number of particles it contains.

Who discovered Avogadro's Number?

Avogadro's Number was first discovered by Italian scientist Amedeo Avogadro in 1811. However, it was not widely accepted until the late 19th century when other scientists such as Stanislao Cannizzaro and Johann Josef Loschmidt provided further evidence for its existence.

What is a mole and how is it related to Avogadro's Number?

A mole is a unit of measurement used in chemistry to express the amount of a substance. One mole is equal to the number of particles in 12 grams of carbon-12, which is approximately 6.022 x 10^23 particles. This number is the same as Avogadro's Number, making it a fundamental constant for calculating the amount of a substance in a given sample.

What are some applications of Avogadro's Number?

Avogadro's Number is used in various fields of science and technology, including chemistry, physics, and materials science. It is essential for calculating the amount of reactants and products in chemical reactions, determining the molecular weight of compounds, and understanding the properties of materials at the atomic level. It is also used in industries such as pharmaceuticals, where precise measurements of substances are crucial.

How was Avogadro's Number determined?

Avogadro's Number was initially determined by measuring the volume of gases at different pressures and temperatures. By using Avogadro's Law, which states that equal volumes of gases at the same temperature and pressure contain the same number of particles, scientists were able to calculate the number of particles in one mole of a gas. Modern methods, such as X-ray crystallography and mass spectrometry, have also been used to determine Avogadro's Number with greater accuracy.

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