Determining Fe2+ Concentration by Redox Titration

In summary, redox titration is a method used to determine the concentration of Fe2+ by measuring the amount of oxidizing agent needed to react with all of the reducing agent. Accurately determining the concentration of Fe2+ is important in understanding and controlling chemical and biological systems. The steps involved in conducting a redox titration include preparing a standard solution, adding a known volume of the reducing agent, adding an indicator, and titrating until the endpoint is reached. Common indicators used in this process include ferroin, diphenylamine, and diphenylamine sulfonate. Some potential sources of error include improper preparation of the standard solution, inaccurate measurements, and human error. It is important to follow precise techniques to
  • #1
yuuri14
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iron(ii) can be determined by redox titration with a cerium (iv) solution. the oxidation reduced reaction is fe2+ + ce2+ = fe3+ + ce3+

what is the concentration of fe2+ if it requires 21.35mL of .3136 ce4+ to titrate a 10.00mL aliquot to the endpoint.
 
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  • #3


I would like to first clarify the purpose of this experiment. The determination of Fe2+ concentration by redox titration is a common method used in analytical chemistry to quantify the amount of iron present in a solution. In this particular experiment, we are using a cerium (IV) solution as the titrant, which means it is the substance that reacts with the analyte (Fe2+) to determine its concentration.

Based on the given information, we can calculate the concentration of Fe2+ using the following formula:

Fe2+ concentration = (volume of Ce4+ titrant * concentration of Ce4+ titrant) / volume of Fe2+ aliquot

Substituting the values given in the question, we get:

Fe2+ concentration = (21.35 mL * 0.3136 M) / 10.00 mL = 0.669 M

Therefore, the concentration of Fe2+ in the given solution is 0.669 M. It is important to note that this value may vary depending on the accuracy and precision of the experimental procedure. Further replicates of the experiment and proper calibration of equipment can help improve the accuracy of the results.
 

1. How does redox titration determine the concentration of Fe2+?

Redox titration involves a chemical reaction between a reducing agent (Fe2+) and an oxidizing agent, where the amount of oxidizing agent needed to react with all of the reducing agent is used to calculate the concentration of the reducing agent.

2. What is the importance of determining the concentration of Fe2+?

Fe2+ is an important ion in many chemical and biological systems, and its concentration can affect the overall reactivity and stability of these systems. Therefore, accurately determining its concentration is crucial for understanding and controlling these processes.

3. What are the steps involved in conducting a redox titration for Fe2+ concentration?

The steps typically involve preparing a standard solution of the oxidizing agent, adding a known volume of the reducing agent to a flask, adding an indicator to the flask, and titrating the solution with the standard solution until the indicator changes color. The volume of the standard solution used can then be used to calculate the concentration of the reducing agent.

4. What indicators are commonly used in redox titration for Fe2+ concentration?

Some common indicators used in redox titration for Fe2+ concentration include ferroin, diphenylamine, and diphenylamine sulfonate. These indicators undergo a color change when the endpoint of the titration is reached, indicating the completion of the reaction.

5. What are some sources of error in determining Fe2+ concentration by redox titration?

Some potential sources of error include improper preparation of the standard solution, inaccurate measurements of volumes, incomplete or slow reactions between the reducing and oxidizing agents, and human error in reading the endpoint of the titration. It is important to carefully follow the steps and use precise techniques to minimize these sources of error.

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