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can someone give me an example of isolated open systems ,which can allow me to understand 2nd law of thermodynamics?,bcoz i don't think there's anything called open system and that too in isolation
The term is poorly chosen, but what it's referring to is an isolated system containing more than one species of particles that can interact and turn into one another. It's 'open' in the sense that the Nk's are not constant, and therefore to discuss equilibrium you need to talk about the chemical potentials.