Help Ravi Selectively Etch GaAs w.r.to Al0.3Ga0.7As

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In summary, the conversation discusses the selective etching of GaAs with regards to Al0.3Ga0.7As using different compositions such as citric acid and hydrogen peroxide. However, the literature does not provide successful results. Suggestions for alternative etching methods such as using fluoride or chloride ions are given, but caution is advised with corrosive acids like HF. The use of citric acid, succinic acid, and sodium fluoride are also mentioned as potential options. The conversation also references a study on highly selective etching of GaAs using a citric acid/H2O2/H2O etching system.
  • #1
physics2010
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Can anyone please help me with the selective etching of GaAs w.r.to Al0.3Ga0.7As..
I have tried out many compositions using the citric acid and hydrogen peroxide and none of them given in the literature work...Please help

Ravi
 
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  • #2
Selective etching might require an electric current or polarization. Also Al is perhaps better etch with a fluoride or chloride ion present. HF/HCl in HNO3 might work. Be very careful with HF - it's nasty stuff.

However, I'm not familiar with Al-Ga-As.
 
  • #3
Thanks for the reply..but i am afraid we cannot use corrosive acids like HF.. So please tell if u are familiar with acids like citric acid, succinic acid.etc..
 
  • #4
Have you already done the literature search? I looked up gaas etching on Google, and got this one on the first page:

Liao, C., Houng, M., and Wang, Y. "Highly Selective Etching of GaAs on Al0.2Ga0.8As Using Citric Acid/H2O2/H2O Etching System". Electrochem. Solid-State Lett., Volume 7, Issue 11, pp. C129-C132 (2004)
http://dx.doi.org/10.1149/1.1803072
 
  • #5
You don't have to use HF - it can be enough to add F- (for example sodium fluoride) to get the same effect. Still, you have to be cautious.

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1. What is the purpose of selectively etching GaAs w.r.to Al0.3Ga0.7As?

Selective etching is used to remove specific materials from a substrate, such as GaAs, while leaving other materials intact, such as Al0.3Ga0.7As. This process is commonly used in semiconductor device fabrication to create precise patterns or structures on a substrate.

2. How does selective etching work?

Selective etching works by using a chemical solution or plasma that can selectively dissolve or etch certain materials while leaving others untouched. The selectivity of the etching process is determined by the chemical properties of the etchant and the materials being etched.

3. What are the benefits of selectively etching GaAs w.r.to Al0.3Ga0.7As?

Selective etching allows for precise control over the patterns and structures created on a substrate. This is important in semiconductor device fabrication as it can improve device performance and yield. It also allows for the creation of complex devices with multiple layers of different materials.

4. What is the role of Al0.3Ga0.7As in the selective etching process?

Al0.3Ga0.7As serves as a mask or protective layer during the etching process. It is resistant to the etchant being used, so it protects the underlying GaAs from being etched away. This allows for the selective removal of only the GaAs material.

5. What are some common etchants used for selectively etching GaAs w.r.to Al0.3Ga0.7As?

Some common etchants for this process include hydrofluoric acid (HF) and citric acid (C6H8O7). These etchants have a high selectivity for GaAs over Al0.3Ga0.7As and can be controlled to achieve precise etching depths. Other etchants, such as potassium hydroxide (KOH) and sulfuric acid (H2SO4), can also be used for selective etching depending on the specific materials and desired results.

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