Silver-Cadmium Electrochemical Cell

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SUMMARY

The discussion focuses on the construction and functioning of a Silver-Cadmium electrochemical cell using silver wire, cadmium wire, and their respective nitrate solutions. The cell operates by oxidizing cadmium (Cd) to cadmium ions (Cd2+) while reducing silver ions (Ag+) to silver metal (Ag). The net ionic equation for the reactions is 2Ag+(aq) + Cd(s) → Cd2+(aq) + 2Ag(s). The copper wire serves as a conductor, providing a pathway for electron flow between the electrodes.

PREREQUISITES
  • Understanding of electrochemical cells and their components
  • Familiarity with oxidation and reduction reactions
  • Knowledge of ionic equations and their balancing
  • Basic principles of electron flow in circuits
NEXT STEPS
  • Research the Nernst equation for calculating cell potential
  • Explore the concept of electrochemical series and its applications
  • Learn about different types of electrochemical cells, including galvanic and electrolytic cells
  • Investigate the effects of concentration on cell voltage using the Nernst equation
USEFUL FOR

Chemistry students, electrochemists, and anyone interested in understanding the principles of electrochemical cells and their applications in energy storage and conversion.

Wardling
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You are given the following materials:
 Silver wire
 A 0.10 mol L-1 solution of cadmium nitrate
 Cadmium wire
 A 0.10 mol L-1 solution of silver nitrate
 A salt bridge
 Copper wire
 Beakers and other glassware as required
Draw a labelled sketch of your cell. Describe how the electrochemical cell will function. Include equations for the reactions and what you would expect to see happen.

I know that if I ignore the copper wire, I can put the AgNO3 and the Ag wire into one beaker, and the Cd(NO3)2 and Cd wire into another beaker. I can connect the two using the salt bridge. The electrons will flow from the Cd to the Ag. The Cd will be oxidised (Cd >><< Cd2+ + 2e-), and the Ag will be reduced (2AG+ + 2e- >><< 2Ag). The net ionic equation is: 2Ag+(aq) + Cd(s) >><< Cd2+(aq) + 2Ag(s).

My question is what does the copper wire do? Is it to make the current reversible? Or for plating?
 
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Silly me, the copper wire connects the two electrodes providing a path for the electrons to travel through!
 

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