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Smallest Heat of Comb.

  1. Jan 22, 2006 #1
    Which isomer of C5H10 would you expect to have the smallest heat of combustion?
    A. cyclopentane
    D. cis-1,2-Dimethylcyclopentane
    E. trans-1,2-Dimethylcyclopentane

    .. I'm thinking A because there are no groups.. can I please be confirmed?o:)
  2. jcsd
  3. Jan 23, 2006 #2


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    I will confirm to you that you are guessing, then I'll throw you a bone. Somewhere in your text or class notes, you've been given information on heats of formation of bonds (C-C σ, C-C &pi, C-H), or heats of formation of hydrocarbons (alkenes, alkanes). Give you something to think on?
  4. Jan 23, 2006 #3

    cis-1,2-dimethylcyclopropane has a larger negative heat of combustion than trans-1,2-Dimethylcyclopropane.

    The c-c bonds in cyclopropane are bent... which makes for weaker bonds.. so now its E
  5. Jan 23, 2006 #4
    haha im just messing with you.. It's Definitely A.. According to research =P
  6. Jan 23, 2006 #5
    Ok.. Final Answer...

    I changed my mind.. to have the smallest heat of combustion, the compound must be the least stable..
    and if we had 5 choices:
    A) Cyclopentane
    B) Methylcyclopropane
    D) cis-1,2-dimethylcyclopropane
    E) trans-1,2-Dimethylcyclopropane

    C) would have the smallest heat of combustion because it is least stable...
    due to the interaction of the two methyl groups... that are located CLOSEST together...
    hmmm.. is that a good reasoning? So.. C)1,1-Dimethylcyclopropane
  7. Jan 23, 2006 #6
    EASY TO BREAK = SMALLEST HEAT OF COMBUSTION??? is that true?:confused:
  8. Jan 23, 2006 #7


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    You're thinking about the right things, but you came up just slightly backward for a result. Everything winds up at the same enthalpy when it's combusted, carbon dioxide plus water in the same stoichiometry. Now how do the starting enthalpy levels compare to one another? Methylcyclobutane has a lot of ring strain, enough so that it has a positive enthalpy of formation relative to hydrogen and carbon. Cyclopentane is slightly strained, but not much, and has a negative enthalpy of formation. Formation of water and carbon dioxide from oxygen and these two isomers is accompanied by an enthalpy change that is the difference between h-carbon plus oxygen and water plus carbon dioxide. Given that the enthalpies of formation of water and carbon dioxide are large and negative, which is the larger difference?
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