How Does pH Affect the Solubility of Mg(OH)2?

In summary, solubility with common ion refers to the decrease in solubility of a salt due to the presence of a common ion in the solution. This is caused by the common ion effect, which disrupts the equilibrium of solute ions and decreases their solubility. Some common ions that can affect solubility include chloride, sulfate, and carbonate ions. The common ion effect can be used to control the solubility of a salt by adding a common ion to decrease solubility and allow for precipitation. It can be minimized by diluting the solution, adding a complexing agent, or changing the pH.
  • #1
jesuslovesu
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Homework Statement


What is the solubility of Mg(OH)2 in a solution buffered at pH 8.80.

Homework Equations


The Attempt at a Solution


The answer is .45 M or 26 g/L but I can't get that for some reason.

I can find the concentration of hydroxide [OH-] = 6.3 x 10-6
Mg(OH)2 -> Mg+2 + 2OH-
...0+x,...6.3x10-6 + 2x

1.8x10-11 = x(6.3x10-6 + 2x)^2

x = 1.65 x 10-4 M (neglecting the 6.3 x10-6)
I've also tried solving the cubic with similar results.
Does anyone where I went wrong?
 
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  • #2
Solution is buffered. [OH-] is not 6.3x10-6 + 2x but JUST 6.3x10-6.
 
  • #3


Your attempt at solving the problem is correct. The solubility of Mg(OH)2 in a solution buffered at pH 8.80 is indeed 1.65 x 10-4 M or 26 g/L. The discrepancy in your results may be due to rounding errors or slight variations in the given values. It is also possible that the answer given to you is incorrect. I would suggest double checking your calculations and the given values to determine the source of the discrepancy.
 

What is the definition of solubility with common ion?

Solubility with common ion refers to the phenomenon in which the presence of a common ion in a solution decreases the solubility of a salt. This occurs due to the common ion effect, which is the suppression of ionization of a weak electrolyte in the presence of a strong electrolyte.

How does the common ion effect impact solubility?

The common ion effect decreases the solubility of a salt by shifting the equilibrium of the solute ions towards the solid phase, making it less likely for the salt to dissolve in the solution. This is due to the increase in ionic strength caused by the common ion, which disrupts the equilibrium of the solute ions and decreases their solubility.

What are some common ions that can affect solubility?

Some common ions that can affect solubility include the chloride ion (Cl-), sulfate ion (SO42-), and carbonate ion (CO32-). These ions are often found in salts and can decrease the solubility of other salts when present in a solution.

Can the common ion effect be used to control the solubility of a salt?

Yes, the common ion effect can be used to control the solubility of a salt. By adding a common ion to a solution, the solubility of a salt can be decreased, allowing for the precipitation of the salt. This can be useful in various applications such as water treatment and chemical separations.

How can the common ion effect be minimized?

The common ion effect can be minimized by diluting the solution or by adding a complexing agent that can bind to the common ion and decrease its concentration in the solution. Additionally, changing the pH of the solution can also help minimize the common ion effect.

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