Temp Effects on Forward & Reverse Rate Constants

In summary, an increase in temperature can affect the rate constant of both the forward and reverse reactions, but the extent of the effect depends on the \Delta H of the system. It is important to specify the temperature when giving a value for Ke because it is a thermodynamic property that can change with temperature. This is especially important for reactions that are not at equilibrium, as the value of Ke can vary significantly at different temperatures. Additionally, specifying the temperature allows for accurate comparison of Ke values between different reactions.
  • #1
BH20
78
0
What would be the effect of an increase in temp on the rate constant of
a) the forward reaction
b) reverse reaction


and my second Q is..why is it important to specify the temp when giving a value for Ke?

Thanks
 
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  • #2
You may want to elaborate on your questions. Example, are you referring to chemical reactions? Just to give you a hint, it is a good idea to describe how you would answer the questions or what you don't understand about them. Then we can help steer you in the right direction. :wink:
 
  • #3
BH20 said:
What would be the effect of an increase in temp on the rate constant of
a) the forward reaction
b) reverse reaction

and my second Q is..why is it important to specify the temp when giving a value for Ke?
Going further upon what Ouabache has said, the answer to the first question depends on what the [itex]\Delta H[/itex] of the system is. It is not possible to say that this will happen to the forward reaction because you do not know if it is exothermic or endothermic.

Am I to assume that this is a question related to dynamic equilibrium?

The Bob (2004 ©)
 

1. How does temperature affect the forward rate constant?

As temperature increases, the forward rate constant also increases. This is because at higher temperatures, molecules have more kinetic energy, leading to more frequent and energetic collisions between reactant molecules, resulting in a higher rate of product formation.

2. Why does the reverse rate constant decrease with increasing temperature?

The reverse rate constant decreases with increasing temperature because the equilibrium constant, which is the ratio of the forward and reverse rate constants, remains constant. As the forward rate constant increases, the reverse rate constant must decrease in order to maintain this equilibrium constant.

3. How does temperature affect the equilibrium constant?

Temperature has a direct effect on the equilibrium constant. An increase in temperature favors the forward reaction, leading to a higher equilibrium constant. Conversely, a decrease in temperature favors the reverse reaction, resulting in a lower equilibrium constant.

4. Can temperature changes affect the direction of a reaction?

Yes, temperature changes can affect the direction of a reaction. As mentioned before, changes in temperature can alter the equilibrium constant, which determines the direction of a reaction. If the equilibrium constant increases, the reaction will favor the products and vice versa.

5. Is there a limit to how much temperature can affect the rate constants?

Yes, there is a limit to how much temperature can affect the rate constants. As temperature increases, the rate constants will also increase up to a certain point. However, at extremely high temperatures, the rate constants may start to decrease due to other factors such as changes in the structure and stability of molecules.

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