Standard Reduction Potentials Question

In summary, the correct statements are a) Cu2+ ions can be reduced by H2(g) and d) Cu can reduce Sn2+. The incorrect statements are b) Cu can be oxidised by H+ and c) Sn2+ ions can be oxidised by H2(g). The reduction potential values of Cu and Sn determine which reactions are possible.
  • #1
zorro
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Homework Statement



Which of the following statements is correct if
Standard reduction potentials of Cu and Sn are 0.337V and -0.136V resp. (both from +2 charge)

a) Cu2+ ions can be reduced by H2(g)
b) Cu can be oxidised by H+
c) Sn2+ ions can be oxidised by H2(g)
d) Cu can reduce Sn2+

I am confused between reduction/oxidation of ions/metals by H2 or H+. I don't have any idea of correctly employing the given reduction potential values in each case. I tried and deduced that c) and d) must be incorrect. No idea about a) and b)

Please provide me clear explanation of this.
Thanks in advance.
 
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  • #2
Homework EquationsNoneThe Attempt at a Solutiona) Cu2+ ions can be reduced by H2(g) - Correctb) Cu can be oxidised by H+ - Incorrect (Cu is already in the +2 oxidation state, so it cannot be oxidized any further)c) Sn2+ ions can be oxidised by H2(g) - Incorrect (Sn has a more negative reduction potential than H2, so it cannot be oxidized by H2)d) Cu can reduce Sn2+ - Correct
 

What is a standard reduction potential?

A standard reduction potential (SRP) is a measure of the tendency of a substance to undergo reduction (gain electrons) in a chemical reaction. It is measured in volts (V) and reflects the strength of the oxidizing or reducing agent.

How is a standard reduction potential determined?

A standard reduction potential is determined by measuring the voltage of a cell containing the substance in question and a reference electrode, typically the standard hydrogen electrode. The more positive the voltage, the stronger the oxidizing agent. The more negative the voltage, the stronger the reducing agent.

What is the significance of a standard reduction potential?

A standard reduction potential is an important tool in predicting the direction and feasibility of a chemical reaction. If the SRP of the reactant is more positive than that of the product, the reaction is likely to occur spontaneously. If the SRP of the reactant is more negative than that of the product, an external energy source is needed for the reaction to occur.

How does temperature affect standard reduction potentials?

Temperature can affect standard reduction potentials by changing the rate of a reaction. As temperature increases, the rate of a reaction typically increases as well, which can change the observed SRP. However, the SRP itself is an intrinsic property of a substance and does not change with temperature.

What are some real-life applications of standard reduction potentials?

Standard reduction potentials are used in various fields of science, including chemistry, biology, and environmental science. They can be used to predict the outcome of redox reactions in batteries, corrosion processes, and metabolic reactions in living organisms. They are also used in wastewater treatment and in the production of metals.

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