1. The problem statement, all variables and given/known data There is a solid that can be in two phases, with energies U1(S,V) = S2/a1 + b1V(V-2Vo) and U2(S,V) = S2/a2 + b2V(V-2Vo). Consider a phase transition between the two phases at zero pressure. At what temperature, T0, does it occur? 2. Relevant equations T = ∂G/∂S dP/dT = L/TΔV 3. The attempt at a solution I'm not sure about all the equations that would be relevant. I was thinking that I would need to use the Clausius-Clapeyron relation but if P = 0 then that gets me nowhere. Then I thought about setting the Gibbs free energy at each phase equal to each other which would give me S2/a1 + b1V(V-2Vo) - TS = U2(S,V) = S2/a2 + b2V(V-2Vo) - TS but the TS on each side would cancel out and I wasn't sure what I would have to do in order to get T0. Am I going in the completely wrong direction in trying to figure this out?