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The 465 complex

  1. Apr 30, 2015 #1
    1. The problem statement, all variables and given/known data
    I found out this reaction series in my textbook which is as:
    ##2Cu(NO_3)_2+2Na_2S_2O_3 \longrightarrow Cu_2(NO_3)_2 +Na_2S_4O_6+2NaNO_3##
    ## Cu_2(NO_3)_2+Na_2S_2O_3 (excess) \longrightarrow Na_4[Cu_6(S_2O_3)_5] ##
    Though it is not balanced(latter one) but my question is about the complex that is formed. What is it's geometry and what is the hybridisation of ##Cu## in this complex?

    2. Relevant equations


    3. The attempt at a solution
    I don't know. I have never seen any thing like this before. It's an awkward looking compound but still I have curiosity how these type of monsters are made up.
     
  2. jcsd
  3. May 6, 2015 #2
    Thanks for the post! This is an automated courtesy bump. Sorry you aren't generating responses at the moment. Do you have any further information, come to any new conclusions or is it possible to reword the post?
     
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