What is the theory behind Scanning Tunneling Microscopy (STM) technique?

In summary, Scanning tunneling microscopy (STM) is a technique that uses an atomically-sharp metal tip to image the surfaces of conducting materials with atomic-scale resolution. A small tunneling current flows between the tip and the surface when they are connected to a voltage source, and this current can be measured to produce a topographic map of the surface. More information and tutorials on STM can be found online, and IBM Almaden Labs uses the technique for materials synthesis.
  • #1
ovidiut
1
0
hi to everyone!
who can help me with a almost and understandable complete theory of Scanning tunneling Microscopy technique?
with my best wishes
O.
 
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  • #2
There are entire books written on the theory of STM.

From: http://www.chemistry.adelaide.edu.au/external/soc-rel/content/stm.htm
Scanning-tunneling microscopy (STM) can image surfaces of conducting materials with atomic-scale resolution. It uses an atomically-sharp metal tip that is brought very close to the surface. When the tip and sample are connected with a voltage source, a small tunneling current flows between the tip and sample surface. This current can be measured, and the magnitude depends on the distance between the tip and the surface. As the tip is moved laterally across the surface, a feedback mechanism moves the tip up and down to maintain a constant tunneling current. Rastering the tip across the surface therefore produces a topographic map of the surface.

More detailed explanation :
http://www.llnl.gov/str/Scan.html

Tutorials and problems :
http://www.chembio.uoguelph.ca/educmat/chm729/STMpage/stmtutor.htm

IBM Almaden Labs uses the STM as a materials synthesis tool (to perform atomic re-arrangements) - their image gallery is really neat :
http://www.almaden.ibm.com/vis/stm/stm.html
 
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  • #3


Hello O,

The Scanning Tunneling Microscopy (STM) technique is a powerful tool used in nanotechnology and materials science to study the surface of materials at the atomic level. It was invented in 1981 by Gerd Binnig and Heinrich Rohrer, who were awarded the Nobel Prize in Physics in 1986 for their work.

The basic principle of STM is based on the phenomenon of quantum tunneling, where electrons can pass through a potential barrier even if they do not have enough energy to overcome it. In STM, a sharp conducting tip is brought very close to the surface of the sample being studied. A small voltage is applied between the tip and the sample, creating a tunneling current between them. By scanning the tip across the surface and measuring the changes in the tunneling current, a topographic map of the surface can be created with atomic resolution.

The resolution of STM is based on the sharpness of the tip and the sensitivity of the current measurement. The tip is typically made of tungsten or platinum-iridium and is sharpened to a fine point using electrochemical etching. The current measurement is done using a feedback system, where the distance between the tip and the sample is adjusted to keep the tunneling current constant. This allows for precise control of the tip-sample distance, resulting in atomic-scale resolution.

One of the key advantages of STM is its ability to study surfaces in their natural state, without the need for any special preparation or coating. This makes it a valuable tool for studying the properties of various materials, including metals, semiconductors, and insulators. It has also been used to study biological molecules such as DNA and proteins.

In addition to topographic mapping, STM can also be used for other types of measurements, such as spectroscopic analysis and manipulation of individual atoms and molecules. It has opened up new avenues of research in fields such as materials science, surface chemistry, and nanotechnology.

I hope this helps to provide a basic understanding of the theory behind STM. If you have any further questions or need clarification, please let me know.

Best wishes,
 

1. What is the STM technique?

The STM (Scanning Tunneling Microscopy) technique is a scientific method used to image and manipulate surfaces at the atomic level. It uses a sharp probe to scan a sample surface and measures the tunneling current between the probe and the surface to create a 3D image of the surface topography.

2. How does the STM technique work?

The STM technique works by using a sharp probe made of a conducting material, such as metal, to scan a sample surface. The probe is positioned a few nanometers above the surface and a small voltage is applied between the probe and the surface. This creates a tunneling current between the two, which is then measured and used to generate a topographic image of the surface.

3. What are the advantages of using the STM technique?

The STM technique has several advantages, including its ability to image surfaces at the atomic level with high resolution, its non-destructive nature, and its ability to work in a variety of environments, such as in air, vacuum, and liquid. It also allows for the manipulation of individual atoms, making it a valuable tool for nanotechnology research.

4. What are the limitations of the STM technique?

One limitation of the STM technique is that it can only be used on conducting or semi-conducting surfaces, as non-conductive surfaces will not produce a tunneling current. Additionally, the sample must be relatively flat and stable, as any movement or vibration can affect the accuracy of the images. The STM technique also has a limited depth of field and cannot provide information on the chemical composition of a sample.

5. How is the STM technique used in scientific research?

The STM technique has a wide range of applications in scientific research, including in the fields of physics, chemistry, and materials science. It is used to study the properties of various surfaces, such as metals, semiconductors, and biological materials. It is also used to investigate the behavior of individual atoms and molecules, as well as to manipulate and assemble them for potential applications in nanotechnology and molecular electronics.

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