How to derive U(S(V,T),V) from U(S,V,N)?

In summary, the conversation is discussing how to derive the relation U(S(V,T),V) from the given equation U(S,V,N) and the chain rule is used to explain the transition. The solution to the exercise is provided in a given resource and the question is clarified by stating that N is constant, simplifying the equation to U(S,V).
  • #1
Persefonh
3
0

Homework Statement


My question is how can one derive U(S(V,T),V) from the relation U(S,V,N).This is the beginning of a given solution which is not explained in more detail.

Homework Equations

The Attempt at a Solution


I can understand U(S,V,N) as dU=TdS-pdV+μdN but not the transition: U(S,V,N)-->U(S(V,T),V).
A full solution of this exercise is given at http://www.thphys.uni-heidelberg.de/~amendola/statphys/problems-students.pdf on page 3.
 
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  • #2
Are you referring to eqn 13?? If that's the case here's explanation:

[itex]
\frac{\partial U(S,V)}{\partial V}= \frac{\partial U}{\partial S} \frac{\partial S}{\partial V}+\frac{\partial U}{\partial V} \frac{\partial V}{\partial V}
=\frac{\partial U}{\partial S} \frac{\partial S}{\partial V}+\frac{\partial U}{\partial V}
[/itex]

This is a simple chain rule. If you don't know chain rule, review your calculus course, I don't think you'll go anywhere without that.
 
  • #3
Thank you for your reply.I am not referring to equation 13, but before that.
The exercise starts with U(S(V,T),V). My question is how one can derive that from U(S,V,N)?
 
  • #4
Entropy is a function of T,V or T,P.
If you still can't recall,
[itex]S=-\frac{\partial G(T,V)}{\partial T}[/itex] and,
[itex]S=-\frac{\partial A(T,P)}{\partial T}[/itex]
 
Last edited:
  • #5
Hello Persephone, welcome to PF :smile: !

Could it be as simple as N is constant, hence ##U(S, V, N) = U(S, V)## ?
 
  • #6
Thanks BvU!
 

1. What is a thermodynamic potential?

A thermodynamic potential is a function that describes the state of a thermodynamic system in terms of its state variables, such as temperature, pressure, and volume. It represents the total energy of the system and can be used to calculate other thermodynamic properties.

2. How many types of thermodynamic potentials are there?

There are four types of thermodynamic potentials: internal energy, enthalpy, Helmholtz free energy, and Gibbs free energy. Each potential is useful for describing different aspects of a thermodynamic system and can be derived from the others.

3. What is the difference between an extensive and intensive thermodynamic potential?

An extensive thermodynamic potential is proportional to the size or amount of a system, while an intensive thermodynamic potential is independent of the system's size. For example, internal energy is an extensive potential, while temperature is an intensive potential.

4. How is a thermodynamic potential related to entropy?

A thermodynamic potential is closely related to entropy, as it is a measure of a system's ability to do work. The change in a thermodynamic potential is related to the change in entropy through the second law of thermodynamics, which states that the total entropy of an isolated system cannot decrease.

5. How are thermodynamic potentials used in practical applications?

Thermodynamic potentials are used in many practical applications, such as in the design of engines and power plants. They are also used in chemical reactions to determine the feasibility and spontaneity of a reaction. In materials science, thermodynamic potentials are used to predict phase transitions and properties of materials under different conditions.

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