Thermodynamic Proof: Calculating (∂H/∂T)V

  • #1
Themanslayer
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Homework Statement



(∂H/∂T)V = CP( 1 - αPμJT / κT)

Homework Equations


1. dH=TdS + VdP
2. dU= Tds - PdV
3. all maxwell relations
4. every equation here: http://en.wikipedia.org/wiki/Bridgman's_thermodynamic_equations

The Attempt at a Solution


- divided equation 1 by (dT)_v
-used cyclic rule
- used maxwells relations

The closest answer I have obtained is the following:
(∂H/∂T)V = T(∂S/∂T)V + VαP / κT

Any help is appreciated.
 
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