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Thermodynamics Chemical Potential

  1. Oct 19, 2014 #1
    1. The problem statement, all variables and given/known data

    Consider a monatomic ideal gas that lives at a height z above sea level, so each molecule has potential energy mgz in addition to its kinetic energy.


    (a) Show that the chemical potential is the same as if the gas were at sea level, plus an additional term mgz:


    μ(z) = -kT ln [V (2πmkT)3/2] + mgz

    [N ( h2 ) ]


    (You can derive this result from either the definition μ = -T(∂S/∂N)U,V or the formula μ = (∂U/∂N)S,V).


    (b) Suppose you have two chunks of helium gas, one at sea level and one at height z, each having the same temperature and volume. Assuming that they are in diffusive equilibrium, show that the number of molecules in the higher chunk is


    N(z) = N(0)e-mgz/kT


    2. Relevant equations
    So, what am I attempting to show? That kinetic potential is constant? What will I differentiate with respect to?

    3. The attempt at a solution
     
  2. jcsd
  3. Oct 19, 2014 #2
    μ(z) = -kT*ln[V/N * (2πmkT/h2)3/2 ] +mgz
     
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