Thermodynamics combinatorics

In summary, the conversation discusses a system of two Einstein solids sharing six units of energy and the calculation of the number of possible microstates for each solid. The method involves breaking up the cases and using combinatorial identities such as the binomial coefficient bracket. The total number of microstates for the system is found to be 90.
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http://i.imgur.com/O7iWyCF.jpg

the table on this image shows a system of two einstein solids isolated from the environment. with three oscillators and a total of 6 units of energies (hf). can someone explain to me how they got they're ΩA and ΩB values?
 
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Since there are two solids sharing six units of energy, they first break up the cases (solid A has 0 energy units, solid B has 6 energy units)=(0,6), (1,5), (2,4) , (3,3), (4, 2), (5,1), (6,0). Now your question is: How do I calculate the number of possible microstates there are for each solid in each of those cases? By microstates, I mean number of distinct ways to distribute the energy units among the solids' energy levels.

So let's say we're dealing with the case (2,4). How do we calculate how many possible microstates there are for each solid? Solid A has three oscillators and 2 units of energy. How can we distribute 2 units of energy among the three oscillators of solid A? The possibilities would look something like (1,1,0),(0,1,1),(1,0,1), (2,0,0),(0,2,0),(0,0,2). This means there are six possible microstates for solid A, so ΩA=6. Since there are six total units of energy, the remaining four units of energy are in solid B, which is also made of three oscillators. So we can calculate the number of possible microstates for B by the same counting method: the possible microstates of B are (4,0,0),(0,4,0),(0,0,4),(3,1,0),(3,0,1),(0,3,1),(1,3,0),(1,0,3),(0,1,3),(2,1,1),(1,2,1),(1,1,2),(2,2,0),(0,2,2),(2,0,2), which implies ΩB=15. Thus the total number of microstates for the composite system of both A and B is ΩAΩB=6*15=90 microstates (remembering we have assumed that A has 2 and B has 4).

As the photo you attached suggests, you can use quicker combinatorial identities to derive numbers like this, e.g. the binomial coefficient bracket. As an example of a real crafty combinatorics identity, if we want to calculate how many ways there are to distribute the 6 units of energy among the 6 oscillators (with no assumption about how many each subsystem has), we use the multiset binomial coefficient [see http://en.wikipedia.org/wiki/Binomial_coefficient#Multiset_.28rising.29_binomial_coefficient ] according to :

[tex]\Omega = \left ( \begin{pmatrix} 6 \\ 6\end{pmatrix}\right)= \begin{pmatrix}6+6-1 \\ 6\end{pmatrix} = \frac{(6+6-1)!}{((6+6-1)-6)!6!}=\frac{11!}{5!6!} = 462[/tex] as your book states.

If we wanted to do the example I did earlier--where we assume A has 2 and B has 4--we could write:
[tex]\Omega_A\Omega_B = \left ( \begin{pmatrix} 3 \\ 2\end{pmatrix}\right)\left ( \begin{pmatrix} 3 \\ 4\end{pmatrix}\right)= \begin{pmatrix}3+2-1 \\ 2\end{pmatrix} \begin{pmatrix}3+4-1 \\ 4\end{pmatrix}=\frac{4!}{(4-2)!2!}\frac{6!}{(6-4)!4!}=6 \cdot 15 = 90[/tex]
 
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1. What is the relationship between thermodynamics and combinatorics?

Thermodynamics and combinatorics are both branches of science that deal with the study of systems and their behavior. Thermodynamics focuses on the physical properties and energy transformations of a system, while combinatorics deals with the counting and arrangement of objects. The two fields are closely related as the principles of thermodynamics can be applied to combinatorial problems, such as calculating the number of possible energy states in a system.

2. What is the significance of thermodynamics combinatorics in real-world applications?

Thermodynamics combinatorics has numerous applications in various fields such as chemistry, physics, engineering, and biology. It is used to understand and predict the behavior of complex systems, design efficient processes and machines, and optimize energy usage. For example, in chemical reactions, thermodynamics combinatorics can be used to determine the most favorable reaction pathway and the amount of energy released or absorbed.

3. How does entropy play a role in thermodynamics combinatorics?

Entropy, a measure of disorder or randomness in a system, is a fundamental concept in both thermodynamics and combinatorics. In thermodynamics, entropy is used to quantify the amount of energy that is unavailable to do work. In combinatorics, it is used to calculate the number of possible arrangements or combinations of objects in a system. The relationship between the two is seen in the famous Boltzmann equation, which relates the entropy of a system to the number of possible states it can exist in.

4. Can thermodynamics combinatorics be applied to biological systems?

Yes, thermodynamics combinatorics has many applications in biology, particularly in understanding the behavior of biological molecules and systems. For example, it can be used to analyze the thermodynamic stability of protein structures, the efficiency of biochemical reactions, and the energy requirements of cellular processes. It is also used in the field of bioinformatics to analyze and interpret large data sets of genetic information.

5. How is thermodynamics combinatorics related to statistical mechanics?

Thermodynamics combinatorics and statistical mechanics are two complementary approaches to understanding the behavior of physical systems. Thermodynamics deals with macroscopic properties such as temperature and pressure, while statistical mechanics focuses on the microscopic behavior of individual particles. The two fields are related as the principles of thermodynamics can be derived from statistical mechanics, and combinatorial methods are often used to solve statistical mechanics problems.

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